Synthetic efficiency in enzyme mechanisms involving carbocations: Aristolochene synthase

Keyphrases

• Enzyme Mechanism 100%
• Aristolochene 100%
• Synthetic Efficiency 100%
• Carbocations 100%
• Cyclization 40%
• Germacrene A 40%
• Intramolecular Proton Transfer 40%
• Novel Mechanism 20%
• Farnesyl Pyrophosphate 20%
• Density Functional Calculations 20%
• Alternative Pathway 20%
• Double Bond 20%
• Binding Pocket 20%
• Ab Initio Molecular Orbital 20%
• Pyrophosphate 20%
• Bicyclol 20%
• Proton Shuttle 20%
• Deprotonation 20%
• Enzyme Complex 20%
• Bound Water Molecules 20%
• Proton Transfer Mechanism 20%
• Substrate Enzyme 20%
• Carbon Skeleton 20%
• Reprotonation 20%
• Eudesmane 20%
• Molecular Density 20%

Chemistry

• Carbocation 100%
• Aristolochene 100%
• Proton Transfer 50%
• Germacrene A 50%
• Molecular Orbital 25%
• Deprotonation 25%
• (+)-Aristolochene 25%
• Eudesmane 25%
• Double Bond 25%
• Density Functional Theory 25%
• formation 25%

Biochemistry, Genetics and Molecular Biology

• Synthase 100%
• Enzyme Mechanism 100%
• Proton Transport 50%
• Farnesyl Pyrophosphate 25%
• Deprotonation 25%
• Enzyme Substrate Complex 25%
• Pyrophosphate 25%