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Abstract
The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr6 node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).
Original language | English (US) |
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Pages (from-to) | 1213-1219 |
Number of pages | 7 |
Journal | Chemistry of Materials |
Volume | 28 |
Issue number | 4 |
DOIs | |
State | Published - Feb 23 2016 |
Bibliographical note
Publisher Copyright:© 2016 American Chemical Society.
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Dive into the research topics of 'Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach'. Together they form a unique fingerprint.Projects
- 1 Finished
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Energy Frontier Research Center For Inorganometallic Catalyst Design (DE-SC0012702)
Gagliardi, L. (PI), Cramer, C. (CoI), Lu, C. C. (CoI), Penn, L. (CoI), Stein, A. (CoI) & Truhlar, D. G. (CoI)
U.S. DEPARTMENT OF ENERGY (USDOE)
8/1/14 → 7/31/18
Project: Research project