Synthesis, Structure, and Reactivity of Ru(η6-C6Me6)[η4-C6Me4(CH2)2]. An Unusual Transition-Metal o-Xylylene Complex

John W. Hull; Wayne L Gladfelter

doi:10.1021/om00072a033

Synthesis, Structure, and Reactivity of Ru(η⁶-C₆Me₆)[η⁴-C₆Me₄(CH₂)₂]. An Unusual Transition-Metal o-Xylylene Complex

John W. Hull
, Wayne L Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Deprotonation of [Ru(C₆Me₆)₂]²⁺ generates the new o-xylylene complex Ru(C₆Me₆)[C₆Me₄(CH₂)₂]. The X-ray crystallographic study confirms that the metal is coordinated to the endocyclic diene system. The exocyclic methylenes are nucleophilic and can be reacted with electrophiles in a stepwise manner. This has allowed the isolation of a new exo-(methylene)cyclohexadienyl complex.

Original language	English (US)
Pages (from-to)	1716-1718
Number of pages	3
Journal	Organometallics
Volume	1
Issue number	12
DOIs	https://doi.org/10.1021/om00072a033
State	Published - 1982

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abstract = "Deprotonation of [Ru(C6Me6)2]2+ generates the new o-xylylene complex Ru(C6Me6)[C6Me4(CH2)2]. The X-ray crystallographic study confirms that the metal is coordinated to the endocyclic diene system. The exocyclic methylenes are nucleophilic and can be reacted with electrophiles in a stepwise manner. This has allowed the isolation of a new exo-(methylene)cyclohexadienyl complex.",

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year = "1982",

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AU - Gladfelter, Wayne L

PY - 1982

Y1 - 1982

N2 - Deprotonation of [Ru(C6Me6)2]2+ generates the new o-xylylene complex Ru(C6Me6)[C6Me4(CH2)2]. The X-ray crystallographic study confirms that the metal is coordinated to the endocyclic diene system. The exocyclic methylenes are nucleophilic and can be reacted with electrophiles in a stepwise manner. This has allowed the isolation of a new exo-(methylene)cyclohexadienyl complex.

AB - Deprotonation of [Ru(C6Me6)2]2+ generates the new o-xylylene complex Ru(C6Me6)[C6Me4(CH2)2]. The X-ray crystallographic study confirms that the metal is coordinated to the endocyclic diene system. The exocyclic methylenes are nucleophilic and can be reacted with electrophiles in a stepwise manner. This has allowed the isolation of a new exo-(methylene)cyclohexadienyl complex.

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JF - Organometallics

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ER -

Synthesis, Structure, and Reactivity of Ru(η⁶-C₆Me₆)[η⁴-C₆Me₄(CH₂)₂]. An Unusual Transition-Metal o-Xylylene Complex

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