Synthesis of diarylated aromatic hydrocarbons by dehydroxylation of diols using the titanium(IV) chloride and triethylamine reagent system

Mariappan Periasamy; Mallesh Beesu; Masilamani Shanmugaraja

doi:10.1055/s-0033-1339498

Synthesis of diarylated aromatic hydrocarbons by dehydroxylation of diols using the titanium(IV) chloride and triethylamine reagent system

Mariappan Periasamy, Mallesh Beesu, Masilamani Shanmugaraja

Medicinal Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61-92%) in short reaction times (5-30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl₄/Et₃N reagent system in dichloromethane at 25 °C.

Original language	English (US)
Article number	SS-2013-Z0331-OP
Pages (from-to)	2913-2918
Number of pages	6
Journal	Synthesis (Germany)
Volume	45
Issue number	20
DOIs	https://doi.org/10.1055/s-0033-1339498
State	Published - Aug 20 2013

Keywords

dehydroxylation
diols
polycyclic aromatic hydrocarbons
titanium tetrachloride
triethylamine

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title = "Synthesis of diarylated aromatic hydrocarbons by dehydroxylation of diols using the titanium(IV) chloride and triethylamine reagent system",

abstract = "1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61-92%) in short reaction times (5-30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl4/Et3N reagent system in dichloromethane at 25 °C.",

keywords = "dehydroxylation, diols, polycyclic aromatic hydrocarbons, titanium tetrachloride, triethylamine",

author = "Mariappan Periasamy and Mallesh Beesu and Masilamani Shanmugaraja",

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T1 - Synthesis of diarylated aromatic hydrocarbons by dehydroxylation of diols using the titanium(IV) chloride and triethylamine reagent system

AU - Periasamy, Mariappan

AU - Beesu, Mallesh

AU - Shanmugaraja, Masilamani

PY - 2013/8/20

Y1 - 2013/8/20

N2 - 1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61-92%) in short reaction times (5-30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl4/Et3N reagent system in dichloromethane at 25 °C.

AB - 1,2-Diarylacenaphthylene, 9,10-diarylphenanthrene and 9,10-diarylanthracene derivatives were obtained in good yields (61-92%) in short reaction times (5-30 min) from the corresponding diols with the titanium(III) reagent prepared in situ using the TiCl4/Et3N reagent system in dichloromethane at 25 °C.

KW - dehydroxylation

KW - diols

KW - polycyclic aromatic hydrocarbons

KW - titanium tetrachloride

KW - triethylamine

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JO - Synthesis

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