Synthesis of a bulky bis(imino)pyridine compound: A methodology for systematic variation of steric bulk and energetic implications for metalation

Keyphrases

• Metalation 100%
• Systematic Variation 100%
• Steric Bulk 100%
• Imino 100%
• Bis(imino)pyridine 100%
• Pyridine Compounds 100%
• Carbon Atom 50%
• Relative Energy 50%
• NMR Spectroscopy 25%
• Computational Methods 25%
• Thermodynamics 25%
• Steric Hindrance 25%
• Tert-butyl 25%
• Acetic Acid 25%
• Chloride 25%
• NMR Techniques 25%
• Compound II 25%
• Refluxing 25%
• Magnetic Susceptibility 25%
• Synthetic Methods 25%
• Chloride Complexes 25%
• Synthetic Precursor 25%
• Paramagnetic Species 25%
• Planar Conformation 25%
• Acid Solvent 25%
• Pyridine-3 25%
• Bis(imino)pyridine Ligand 25%
• Single Crystal X-ray Diffraction (SCXRD) 25%
• Alkyl Substituent 25%

Chemistry

• Energetics 100%
• Metalation 100%
• NMR Spectroscopy 66%
• Carbon Atom 66%
• Single Crystal X-Ray Diffraction 33%
• Steric Hindrance 33%
• Acetic Acid 33%
• Magnetic Susceptibility 33%

Material Science

• Nuclear Magnetic Resonance 100%
• Nuclear Magnetic Resonance Spectroscopy 100%
• Magnetic Susceptibility 100%
• Single Crystal X-Ray Diffraction 100%