Synthesis, electrochemical properties, and crystal packing of perfluororubrene

Zhuoran Zhang; William A. Ogden; Victor G. Young; Christopher J. Douglas

doi:10.1039/c6cc03259a

Synthesis, electrochemical properties, and crystal packing of perfluororubrene

Zhuoran Zhang, William A. Ogden, Victor G. Young, Christopher J. Douglas

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Abstract

A synthesis of perfluorinated rubrene is reported. Electrochemical analysis revealed the significantly increased electron affinity of perfluororubrene compared with non-modified rubrene. Crystallographic investigation revealed two polymorphs and a solvate, each displaying twisted backbone conformations of perfluororubrene. Taken together, these results suggest perfluororubrene will find applications as a new n-type semiconductor.

Original language	English (US)
Pages (from-to)	8127-8130
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	52
DOIs	https://doi.org/10.1039/c6cc03259a
State	Published - 2016

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© 2016 The Royal Society of Chemistry.

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10.1039/c6cc03259a

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abstract = "A synthesis of perfluorinated rubrene is reported. Electrochemical analysis revealed the significantly increased electron affinity of perfluororubrene compared with non-modified rubrene. Crystallographic investigation revealed two polymorphs and a solvate, each displaying twisted backbone conformations of perfluororubrene. Taken together, these results suggest perfluororubrene will find applications as a new n-type semiconductor.",

author = "Zhuoran Zhang and Ogden, {William A.} and Young, {Victor G.} and Douglas, {Christopher J.}",

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AU - Zhang, Zhuoran

AU - Ogden, William A.

AU - Young, Victor G.

AU - Douglas, Christopher J.

PY - 2016

Y1 - 2016

N2 - A synthesis of perfluorinated rubrene is reported. Electrochemical analysis revealed the significantly increased electron affinity of perfluororubrene compared with non-modified rubrene. Crystallographic investigation revealed two polymorphs and a solvate, each displaying twisted backbone conformations of perfluororubrene. Taken together, these results suggest perfluororubrene will find applications as a new n-type semiconductor.

AB - A synthesis of perfluorinated rubrene is reported. Electrochemical analysis revealed the significantly increased electron affinity of perfluororubrene compared with non-modified rubrene. Crystallographic investigation revealed two polymorphs and a solvate, each displaying twisted backbone conformations of perfluororubrene. Taken together, these results suggest perfluororubrene will find applications as a new n-type semiconductor.

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ER -

Synthesis, electrochemical properties, and crystal packing of perfluororubrene

Abstract

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