Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4-

Beatrice A. Kelsey; John E. Ellis

doi:10.1039/C39860000331

Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C₅Me₅)M(CO)₄^-

Beatrice A. Kelsey, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Reductive carbonylations at atmospheric pressure of (C₅Me ₅)MCl₃ (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et₄N][(C₅Me₅)M(CO)₄], which contain the first examples of carbonyl anions of titanium and zirconium.

Original language	English (US)
Pages (from-to)	331-332
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39860000331
State	Published - 1986

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10.1039/C39860000331

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Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C₅Me₅)M(CO)₄^-. / Kelsey, Beatrice A.; Ellis, John E.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 1986, p. 331-332.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4-",

abstract = "Reductive carbonylations at atmospheric pressure of (C5Me 5)MCl3 (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.",

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AU - Ellis, John E.

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N2 - Reductive carbonylations at atmospheric pressure of (C5Me 5)MCl3 (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.

AB - Reductive carbonylations at atmospheric pressure of (C5Me 5)MCl3 (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.

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