Reductive carbonylations at atmospheric pressure of (C5Me 5)MCl3 (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - Jan 1 1986|