Synthesis, characterization, and properties of the pentamethylcyclopentadienyltetra-carbonylmetallates(0) of titanium and zirconium. Anionic and carbocyclic derivatives of zerovalent group 4 carbonyls, (C5Me5)M(CO)4-

Beatrice A. Kelsey, John E. Ellis

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26 Scopus citations

Abstract

Reductive carbonylations at atmospheric pressure of (C5Me 5)MCl3 (M=Ti and Zr), conducted at low temperature, provide thermally robust and crystalline products of the general formula [Et4N][(C5Me5)M(CO)4], which contain the first examples of carbonyl anions of titanium and zirconium.

Original languageEnglish (US)
Pages (from-to)331-332
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
StatePublished - Jan 1 1986

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