Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

Blake J. Aronson; Andrew K. Kinser; Stefano Passerini; William H Smyrl; Andreas Stein

doi:10.1021/cm9805828

Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

Blake J. Aronson
, Andrew K. Kinser
, Stefano Passerini
, William H Smyrl
, Andreas Stein

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

Original language	English (US)
Pages (from-to)	949-957
Number of pages	9
Journal	Chemistry of Materials
Volume	11
Issue number	4
DOIs	https://doi.org/10.1021/cm9805828
State	Published - 1999

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10.1021/cm9805828

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title = "Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route",

abstract = "Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.",

author = "Aronson, \{Blake J.\} and Kinser, \{Andrew K.\} and Stefano Passerini and Smyrl, \{William H\} and Andreas Stein",

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TY - JOUR

T1 - Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

AU - Aronson, Blake J.

AU - Kinser, Andrew K.

AU - Passerini, Stefano

AU - Smyrl, William H

AU - Stein, Andreas

PY - 1999

Y1 - 1999

N2 - Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

AB - Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

UR - https://www.scopus.com/pages/publications/3142521443

UR - https://www.scopus.com/pages/publications/3142521443#tab=citedBy

U2 - 10.1021/cm9805828

DO - 10.1021/cm9805828

M3 - Article

AN - SCOPUS:3142521443

SN - 0897-4756

VL - 11

SP - 949

EP - 957

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 4

ER -

Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

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