Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

Blake J. Aronson; Andrew K. Kinser; Stefano Passerini; William H Smyrl; Andreas Stein

doi:10.1021/cm9805828

Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

Blake J. Aronson, Andrew K. Kinser, Stefano Passerini, William H Smyrl, Andreas Stein

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Abstract

Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

Original language	English (US)
Pages (from-to)	949-957
Number of pages	9
Journal	Chemistry of Materials
Volume	11
Issue number	4
DOIs	https://doi.org/10.1021/cm9805828
State	Published - Jan 1 1999

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abstract = "Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.",

author = "Aronson, {Blake J.} and Kinser, {Andrew K.} and Stefano Passerini and Smyrl, {William H} and Andreas Stein",

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T1 - Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

AU - Aronson, Blake J.

AU - Kinser, Andrew K.

AU - Passerini, Stefano

AU - Smyrl, William H

AU - Stein, Andreas

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

AB - Magnesium-substituted birnessite and zinc chalcophanite have been synthesized through a novel procedure based on a combination of coprecipitation and metal ion intercalation techniques. The materials showed very promising performance as hosts for lithium intercalation. Upon galvanostatic discharge, Mg-birnessite and Zn-chalcophanite composite cathodes were able to intercalate > 2 equiv of lithium per mole.

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Synthesis, characterization, and electrochemical properties of magnesium birnessite and zinc chalcophanite prepared by a low-temperature route

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