Synthesis and x-ray crystallography of chiral tropocoronands

Philip J. Chenier, Jason A. Halfen, Tami L. Raguse, Autumn E. Rich, Kathryn E. Splan, Kazuki Yoshioka, Thomas R. Hoye

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The synthesis of several chiral tropocoronands (6 and 7) has been accomplished. These compounds have been shown to complex with various metals. Tropocoronands that have been synthesized include H2(TC-3, cyhex) through H2(TC-6, cyhex) (6) and H2 (TC-3, diphen) through H2(TC-6, diphen) (7). The route is short and the tropocoronands are easily purified by chromatography or recrystallization. Two other groups have been incorporated into tropocoronands, H2(TC-3, binap) (9) and H2(TC-6, pent) (10).

Original languageEnglish (US)
Pages (from-to)487-503
Number of pages17
JournalSynthetic Communications
Volume31
Issue number4
DOIs
StatePublished - Jan 1 2001

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