Synthesis and thermolysis of 3-substituted 3- trimethylsilylcyclopropenes

Tina L. Arrowood; Steven R Kass

doi:10.1016/S0040-4020(99)00276-8

Synthesis and thermolysis of 3-substituted 3- trimethylsilylcyclopropenes

Tina L. Arrowood, Steven R Kass

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO₂Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.

Original language	English (US)
Pages (from-to)	6739-6748
Number of pages	10
Journal	Tetrahedron
Volume	55
Issue number	22
DOIs	https://doi.org/10.1016/S0040-4020(99)00276-8
State	Published - May 28 1999

Keywords

Cyclopropenes
Kinetics
Rearrangements
X-Ray crystallography

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10.1016/S0040-4020(99)00276-8

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title = "Synthesis and thermolysis of 3-substituted 3- trimethylsilylcyclopropenes",

abstract = "The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO2Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.",

keywords = "Cyclopropenes, Kinetics, Rearrangements, X-Ray crystallography",

author = "Arrowood, {Tina L.} and Kass, {Steven R}",

year = "1999",

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TY - JOUR

T1 - Synthesis and thermolysis of 3-substituted 3- trimethylsilylcyclopropenes

AU - Arrowood, Tina L.

AU - Kass, Steven R

PY - 1999/5/28

Y1 - 1999/5/28

N2 - The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO2Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.

AB - The synthesis of 3-substituted-3-(trimethylsilyl)cyclopropenes (X = CO2Et, CHO, CN) is described. Their acid sensitivity and thermal stability was probed and the reaction products were identified. In one case, a novel rearrangement to a Dewar furan maybe involved and this pathway was explored via kinetics and computations.

KW - Cyclopropenes

KW - Kinetics

KW - Rearrangements

KW - X-Ray crystallography

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U2 - 10.1016/S0040-4020(99)00276-8

DO - 10.1016/S0040-4020(99)00276-8

M3 - Article

AN - SCOPUS:0033612104

SN - 0040-4020

VL - 55

SP - 6739

EP - 6748

JO - Tetrahedron

JF - Tetrahedron

IS - 22

ER -

Synthesis and thermolysis of 3-substituted 3- trimethylsilylcyclopropenes

Abstract

Keywords

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