Synthesis and Structure of Mixed Phosphonium-iodonium Ylide

E. D. Matveeva, T. A. Podrugina, Yu K. Grishin, V. V. Tkachev, Viktor Zhdankin, S. M. Aldoshin, N. S. Zefirov

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A mixed phosphonium-iodonium ylide, phenyliodoniumethoxycarbonylmethylenetriphenyl-phosphorane borofluoride, was synthesized. Its structure was established by means of X-ray diffraction analysis. Temperature dependence of 1H, 13C, and 31P spectra of the ylide synthesized was investigated. A dynamic equilibrium between Z and E-isomers was observed.

Original languageEnglish (US)
Pages (from-to)536-541
Number of pages6
JournalRussian Journal of Organic Chemistry
Issue number4
StatePublished - Apr 1 2003

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    Matveeva, E. D., Podrugina, T. A., Grishin, Y. K., Tkachev, V. V., Zhdankin, V., Aldoshin, S. M., & Zefirov, N. S. (2003). Synthesis and Structure of Mixed Phosphonium-iodonium Ylide. Russian Journal of Organic Chemistry, 39(4), 536-541.