Synthesis and structure of an organotitanoxane containing a tetrahedral Ti4O6 cage, [(η5-C5Me 5)Ti]4O6

Laura M Babcock, V. W. Day, W. G. Klemperer

Research output: Contribution to journalArticlepeer-review

75 Scopus citations

Abstract

Base hydrolysis of (η5-C5Me5)TiCl 3 in toluene yields [(η5-C5Me 5)Ti]4O6 which, according to X-ray structural analysis, has an adamantane-like cage structure with a tetrahedral Ti IV4O6 core.

Original languageEnglish (US)
Pages (from-to)858-859
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
StatePublished - Dec 1 1987

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