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Synthesis and structure of amino acid-derived benziodazoles: New hypervalent iodine heterocycles

  • Viktor Zhdankin
  • , Alexey Y. Koposov
  • , Liansheng Su
  • , Vyacheslav V. Boyarskikh
  • , Brian C. Netzel
  • , Victor G Young

Research output: Contribution to journalArticlepeer-review

Abstract

(Matrix presented) New N-functionalized benziodazoles were prepared by the peracetic oxidation of 2-iodobenzamides derived from alanine or valine. X-ray crystal structural analysis of two benziodazole-based phenyliodonium derivatives provides insight into facile interchange between benziodazoles and iminium benziodoxoles under acidic or basic conditions.

Original languageEnglish (US)
Pages (from-to)1583-1586
Number of pages4
JournalOrganic Letters
Volume5
Issue number9
DOIs
StatePublished - May 1 2003

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