Synthesis and structural study of (PPN)2[Fe4Ru 2(CO)22] [PPN = bis(triphenylphosphine)iminium cation]. A cluster containing vertex-connected triangles

Frederic R. Furuya; Wayne L. Gladfelter

doi:10.1039/C39860000129

Synthesis and structural study of (PPN)₂[Fe₄Ru ₂(CO)₂₂] [PPN = bis(triphenylphosphine)iminium cation]. A cluster containing vertex-connected triangles

Frederic R. Furuya, Wayne L. Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Reaction of (PPN)₂[Fe₃(CO)₁₁] [PPN = bis(triphenylphosphine)iminium cation] with Fe₂Ru(CO)₁₂ gives the hexanuclear dianion [Fe₄Ru₂(CO) ₂₂]^2-; X-ray structural analysis shows that this dianion exhibits an unusual arrangement of vertex-connected triangles.

Original language	English (US)
Pages (from-to)	129-130
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39860000129
State	Published - Jan 1 1986

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10.1039/C39860000129

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title = "Synthesis and structural study of (PPN)2[Fe4Ru 2(CO)22] [PPN = bis(triphenylphosphine)iminium cation]. A cluster containing vertex-connected triangles",

abstract = "Reaction of (PPN)2[Fe3(CO)11] [PPN = bis(triphenylphosphine)iminium cation] with Fe2Ru(CO)12 gives the hexanuclear dianion [Fe4Ru2(CO) 22]2-; X-ray structural analysis shows that this dianion exhibits an unusual arrangement of vertex-connected triangles.",

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AU - Gladfelter, Wayne L.

PY - 1986/1/1

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N2 - Reaction of (PPN)2[Fe3(CO)11] [PPN = bis(triphenylphosphine)iminium cation] with Fe2Ru(CO)12 gives the hexanuclear dianion [Fe4Ru2(CO) 22]2-; X-ray structural analysis shows that this dianion exhibits an unusual arrangement of vertex-connected triangles.

AB - Reaction of (PPN)2[Fe3(CO)11] [PPN = bis(triphenylphosphine)iminium cation] with Fe2Ru(CO)12 gives the hexanuclear dianion [Fe4Ru2(CO) 22]2-; X-ray structural analysis shows that this dianion exhibits an unusual arrangement of vertex-connected triangles.

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Synthesis and structural study of (PPN)₂[Fe₄Ru ₂(CO)₂₂] [PPN = bis(triphenylphosphine)iminium cation]. A cluster containing vertex-connected triangles

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