Synthesis and mass spectra of furylcyclopropyl and furfurylidene ketones

V. I. Kadentsev, V. D. Sokovykh, O. S. Chizhov, V. M. Shostakovskii, Robert M Carlson

Research output: Contribution to journalArticle

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Abstract

1. The reaction of furfurylidene ketones with dimethylsulfoxonium methylide leads to the formation of furylcyclopropyl ketones in about 90% yield. 2. Reaction of both the cyclopropane ring and the double bond with the furan ring, leading to the formation of aromatic hydrocarbon ions, occurs in the dissociative ionization upon electron impact of the furylcyclopropyl and furfurylidene ketones.

Original languageEnglish (US)
Pages (from-to)934-938
Number of pages5
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume29
Issue number6
DOIs
StatePublished - Jun 1 1980

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