Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands

Sylvie Pailloux; Cornel Edicome Shirima; Eileen N. Duesler; Karen Ann Smith; Robert T. Paine

doi:10.1016/j.poly.2011.08.012

Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands

Sylvie Pailloux, Cornel Edicome Shirima, Eileen N. Duesler, Karen Ann Smith, Robert T. Paine

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Syntheses for [(diphenylphosphinoyl)methyl-4,5-dihydrooxazole (2) and [(diarylphosphinoyl)methylbenzoxazoles [aryl = phenyl (3), tolyl (4), 2-trifluoromethylphenyl (5) and 3,5-bis(trifluoromethyl)phenyl (6) have been developed. Each ligand has been characterized by spectroscopic methods and single crystal X-ray diffraction analyses have been completed for 2, 3, 4 and 5. The coordination chemistry of the ligands with Nd(NO₃)₃ and Yb(NO₃)₃ has been examined and structure determinations for [Nd(2)₂(NO₃)₃(CH ₃OH), [Nd(2)₂(NO₃)₃, [Yb(3) ₂(NO₃)₃(H₂O)·0.5(CH ₃OH), [Nd(3)₂(NO₃)₃· 3(CHCl₃), [Nd(4)₂(NO₃)₃(H ₂O), [Yb(4)₂(NO₃)₃(H₂O) and [Yb(5)₂(NO₃)₃(H₂O)·0. 5(CH₃CN) are reported. Depending upon conditions, the ligands act as monodentate PO or bidentate, chelating PO,N donors.

Original language	English (US)
Pages (from-to)	2746-2757
Number of pages	12
Journal	Polyhedron
Volume	30
Issue number	16
DOIs	https://doi.org/10.1016/j.poly.2011.08.012
State	Published - Oct 11 2011

Bibliographical note

Funding Information:
Financial support for this study was provided by the US Department of Energy (DoE), Chemical Sciences, Geosciences and Biosciences Office, Office of Basic Energy Sciences (Grant DE-FG02-03ER15419 ) (RTP). In addition, funds from the National Science Foundation assisted the purchase of the X-ray diffractometer (CHE-0443580) and NMR spectrometers (CHE-0840523 and 0946690).

Keywords

Benzoxazole
Lanthanide complexes
Oxazole
Phosphine oxide

Publisher link

10.1016/j.poly.2011.08.012

Find It

Find It at U of M Libraries

Cite this

@article{7f9240bf2b114fce921bc331f60637ed,

title = "Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands",

abstract = "Syntheses for [(diphenylphosphinoyl)methyl-4,5-dihydrooxazole (2) and [(diarylphosphinoyl)methylbenzoxazoles [aryl = phenyl (3), tolyl (4), 2-trifluoromethylphenyl (5) and 3,5-bis(trifluoromethyl)phenyl (6) have been developed. Each ligand has been characterized by spectroscopic methods and single crystal X-ray diffraction analyses have been completed for 2, 3, 4 and 5. The coordination chemistry of the ligands with Nd(NO3)3 and Yb(NO3)3 has been examined and structure determinations for [Nd(2)2(NO3)3(CH 3OH), [Nd(2)2(NO3)3, [Yb(3) 2(NO3)3(H2O)·0.5(CH 3OH), [Nd(3)2(NO3)3· 3(CHCl3), [Nd(4)2(NO3)3(H 2O), [Yb(4)2(NO3)3(H2O) and [Yb(5)2(NO3)3(H2O)·0. 5(CH3CN) are reported. Depending upon conditions, the ligands act as monodentate PO or bidentate, chelating PO,N donors.",

keywords = "Benzoxazole, Lanthanide complexes, Oxazole, Phosphine oxide",

author = "Sylvie Pailloux and Shirima, {Cornel Edicome} and Duesler, {Eileen N.} and Smith, {Karen Ann} and Paine, {Robert T.}",

note = "Funding Information: Financial support for this study was provided by the US Department of Energy (DoE), Chemical Sciences, Geosciences and Biosciences Office, Office of Basic Energy Sciences (Grant DE-FG02-03ER15419 ) (RTP). In addition, funds from the National Science Foundation assisted the purchase of the X-ray diffractometer (CHE-0443580) and NMR spectrometers (CHE-0840523 and 0946690). ",

year = "2011",

month = oct,

day = "11",

doi = "10.1016/j.poly.2011.08.012",

language = "English (US)",

volume = "30",

pages = "2746--2757",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "16",

}

TY - JOUR

T1 - Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands

AU - Pailloux, Sylvie

AU - Shirima, Cornel Edicome

AU - Duesler, Eileen N.

AU - Smith, Karen Ann

AU - Paine, Robert T.

N1 - Funding Information: Financial support for this study was provided by the US Department of Energy (DoE), Chemical Sciences, Geosciences and Biosciences Office, Office of Basic Energy Sciences (Grant DE-FG02-03ER15419 ) (RTP). In addition, funds from the National Science Foundation assisted the purchase of the X-ray diffractometer (CHE-0443580) and NMR spectrometers (CHE-0840523 and 0946690).

PY - 2011/10/11

Y1 - 2011/10/11

N2 - Syntheses for [(diphenylphosphinoyl)methyl-4,5-dihydrooxazole (2) and [(diarylphosphinoyl)methylbenzoxazoles [aryl = phenyl (3), tolyl (4), 2-trifluoromethylphenyl (5) and 3,5-bis(trifluoromethyl)phenyl (6) have been developed. Each ligand has been characterized by spectroscopic methods and single crystal X-ray diffraction analyses have been completed for 2, 3, 4 and 5. The coordination chemistry of the ligands with Nd(NO3)3 and Yb(NO3)3 has been examined and structure determinations for [Nd(2)2(NO3)3(CH 3OH), [Nd(2)2(NO3)3, [Yb(3) 2(NO3)3(H2O)·0.5(CH 3OH), [Nd(3)2(NO3)3· 3(CHCl3), [Nd(4)2(NO3)3(H 2O), [Yb(4)2(NO3)3(H2O) and [Yb(5)2(NO3)3(H2O)·0. 5(CH3CN) are reported. Depending upon conditions, the ligands act as monodentate PO or bidentate, chelating PO,N donors.

AB - Syntheses for [(diphenylphosphinoyl)methyl-4,5-dihydrooxazole (2) and [(diarylphosphinoyl)methylbenzoxazoles [aryl = phenyl (3), tolyl (4), 2-trifluoromethylphenyl (5) and 3,5-bis(trifluoromethyl)phenyl (6) have been developed. Each ligand has been characterized by spectroscopic methods and single crystal X-ray diffraction analyses have been completed for 2, 3, 4 and 5. The coordination chemistry of the ligands with Nd(NO3)3 and Yb(NO3)3 has been examined and structure determinations for [Nd(2)2(NO3)3(CH 3OH), [Nd(2)2(NO3)3, [Yb(3) 2(NO3)3(H2O)·0.5(CH 3OH), [Nd(3)2(NO3)3· 3(CHCl3), [Nd(4)2(NO3)3(H 2O), [Yb(4)2(NO3)3(H2O) and [Yb(5)2(NO3)3(H2O)·0. 5(CH3CN) are reported. Depending upon conditions, the ligands act as monodentate PO or bidentate, chelating PO,N donors.

KW - Benzoxazole

KW - Lanthanide complexes

KW - Oxazole

KW - Phosphine oxide

UR - http://www.scopus.com/inward/record.url?scp=80052948198&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80052948198&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2011.08.012

DO - 10.1016/j.poly.2011.08.012

M3 - Article

AN - SCOPUS:80052948198

VL - 30

SP - 2746

EP - 2757

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 16

ER -

Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands

Abstract

Bibliographical note

Keywords

Publisher link

Find It

Other files and links

Fingerprint

Cite this