Synthesis and characterization of the first 2 D neptunyl structure stabilized by side-on cation-cation interactions

Bess Vlaisavljevich; Pere Mirõ; Dongxia Ma; Ginger E. Sigmon; Peter C. Burns; Christopher J. Cramer; Laura Gagliardi

doi:10.1002/chem.201204149

Synthesis and characterization of the first 2 D neptunyl structure stabilized by side-on cation-cation interactions

Bess Vlaisavljevich, Pere Mirõ, Dongxia Ma, Ginger E. Sigmon, Peter C. Burns, Christopher J. Cramer, Laura Gagliardi

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Cation-cation interaction: A new 2 D sheet structure containing a side-on cation-cation interaction (CCI) has been synthesized and characterized (see figure). Unprecedentedly, no chelating ligands between the cations are present. The nature of the side-on interaction and ligand effects has been explored by using a variety of quantum chemical methods. The spin-orbit-coupled ground state mixes singlet, triplet, and quintet-pure spin states.

Original language	English (US)
Pages (from-to)	2937-2941
Number of pages	5
Journal	Chemistry - A European Journal
Volume	19
Issue number	9
DOIs	https://doi.org/10.1002/chem.201204149
State	Published - Feb 25 2013

Keywords

actinides
cations
density functional calculations
neptunium

Publisher link

10.1002/chem.201204149

Find It

Find It at U of M Libraries

Cite this

@article{4585bcf720e64849a6fc06fd083a4ae0,

title = "Synthesis and characterization of the first 2 D neptunyl structure stabilized by side-on cation-cation interactions",

abstract = "Cation-cation interaction: A new 2 D sheet structure containing a side-on cation-cation interaction (CCI) has been synthesized and characterized (see figure). Unprecedentedly, no chelating ligands between the cations are present. The nature of the side-on interaction and ligand effects has been explored by using a variety of quantum chemical methods. The spin-orbit-coupled ground state mixes singlet, triplet, and quintet-pure spin states.",

keywords = "actinides, cations, density functional calculations, neptunium",

author = "Bess Vlaisavljevich and Pere Mir{\~o} and Dongxia Ma and Sigmon, {Ginger E.} and Burns, {Peter C.} and Cramer, {Christopher J.} and Laura Gagliardi",

year = "2013",

month = feb,

day = "25",

doi = "10.1002/chem.201204149",

language = "English (US)",

volume = "19",

pages = "2937--2941",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "9",

}

TY - JOUR

T1 - Synthesis and characterization of the first 2 D neptunyl structure stabilized by side-on cation-cation interactions

AU - Vlaisavljevich, Bess

AU - Mirõ, Pere

AU - Ma, Dongxia

AU - Sigmon, Ginger E.

AU - Burns, Peter C.

AU - Cramer, Christopher J.

AU - Gagliardi, Laura

PY - 2013/2/25

Y1 - 2013/2/25

N2 - Cation-cation interaction: A new 2 D sheet structure containing a side-on cation-cation interaction (CCI) has been synthesized and characterized (see figure). Unprecedentedly, no chelating ligands between the cations are present. The nature of the side-on interaction and ligand effects has been explored by using a variety of quantum chemical methods. The spin-orbit-coupled ground state mixes singlet, triplet, and quintet-pure spin states.

AB - Cation-cation interaction: A new 2 D sheet structure containing a side-on cation-cation interaction (CCI) has been synthesized and characterized (see figure). Unprecedentedly, no chelating ligands between the cations are present. The nature of the side-on interaction and ligand effects has been explored by using a variety of quantum chemical methods. The spin-orbit-coupled ground state mixes singlet, triplet, and quintet-pure spin states.

KW - actinides

KW - cations

KW - density functional calculations

KW - neptunium

UR - http://www.scopus.com/inward/record.url?scp=84874095321&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84874095321&partnerID=8YFLogxK

U2 - 10.1002/chem.201204149

DO - 10.1002/chem.201204149

M3 - Article

C2 - 23362171

AN - SCOPUS:84874095321

SN - 0947-6539

VL - 19

SP - 2937

EP - 2941

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 9

ER -

Synthesis and characterization of the first 2 D neptunyl structure stabilized by side-on cation-cation interactions

Abstract

Keywords

Publisher link

Find It

Other files and links

Fingerprint

Cite this