Synthesis and characterization of model fluorinated block copolymers

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A series of monodispersed polystyrene-b-fluorinated polyisoprene (PS-b-PI) block copolymers was synthesized by the selective insertion of difluorocarbene into the PI block of a preformed PS-b-PI diblock copolymer. The fluorination extent was controlled by the molar ratio of hexafluoropropylene oxide to the double bonds. The narrow molecular weight distribution of the fluorinated products suggested that the polymer chains were modified without side reactions. Small-angle X-ray scattering analysis was used to characterize the morphologies of these novel copolymers. The domain spacings increased significantly with the fluorination extent.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherAmerican Chemical Society
Pages474
Number of pages1
Volume40
Edition1
StatePublished - Mar 1999
EventProceedings of the 1999 ACS Anaheim Meeting - Anaheim, CA, USA
Duration: Mar 21 1999Mar 25 1999

Other

OtherProceedings of the 1999 ACS Anaheim Meeting
CityAnaheim, CA, USA
Period3/21/993/25/99

Fingerprint

Fluorination
Polyisoprenes
Polystyrenes
Block copolymers
Molecular weight distribution
X ray scattering
Oxides
Polymers
Copolymers
difluorocarbene

Cite this

Ren, Y., Hillmyer, M. A., & Lodge, T. P. (1999). Synthesis and characterization of model fluorinated block copolymers. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 40, pp. 474). American Chemical Society.

Synthesis and characterization of model fluorinated block copolymers. / Ren, Yu; Hillmyer, Marc A.; Lodge, Timothy P.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 1. ed. American Chemical Society, 1999. p. 474.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Ren, Y, Hillmyer, MA & Lodge, TP 1999, Synthesis and characterization of model fluorinated block copolymers. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 edn, vol. 40, American Chemical Society, pp. 474, Proceedings of the 1999 ACS Anaheim Meeting, Anaheim, CA, USA, 3/21/99.
Ren Y, Hillmyer MA, Lodge TP. Synthesis and characterization of model fluorinated block copolymers. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 ed. Vol. 40. American Chemical Society. 1999. p. 474
Ren, Yu ; Hillmyer, Marc A. ; Lodge, Timothy P. / Synthesis and characterization of model fluorinated block copolymers. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 1. ed. American Chemical Society, 1999. pp. 474
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