Syntheses of monosubstituted rhodocenium derivatives, monomers, and polymers

Yi Yan; T. Maxwell Deaton; Jiuyang Zhang; Hongkun He; Jeffery Hayat; Parasmani Pageni; Krzysztof Matyjaszewski; Chuanbing Tang

doi:10.1021/acs.macromol.5b00471

Syntheses of monosubstituted rhodocenium derivatives, monomers, and polymers

Yi Yan
, T. Maxwell Deaton
, Jiuyang Zhang
, Hongkun He
, Jeffery Hayat
, Parasmani Pageni
, Krzysztof Matyjaszewski
, Chuanbing Tang

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

We report the first chemoselective, high yield synthesis of monosubstituted rhodocenium through a " η⁵ → η⁴ → η⁵" strategy detailing sequential nucleophilic addition and endohydride abstraction. Monosubstituted rhodocenium derivatives are then used as versatile synthons for the preparation of the first-ever vinyl monomers that allow controlled polymerizations including ROMP and RAFT, leading to rhodocenium-containing metallopolymers. Exploratory ion-exchange and self-assembly of this new class of polyelectrolytes cultivates the potential of side-chain rhodocenium-containing polymers.

Original language	English (US)
Pages (from-to)	1644-1650
Number of pages	7
Journal	Macromolecules
Volume	48
Issue number	6
DOIs	https://doi.org/10.1021/acs.macromol.5b00471
State	Published - Mar 24 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

Publisher link

10.1021/acs.macromol.5b00471

Find It

Find It at U of M Libraries

Cite this

@article{dfd3f15263cd482297bb3c770c9e80d9,

title = "Syntheses of monosubstituted rhodocenium derivatives, monomers, and polymers",

abstract = "We report the first chemoselective, high yield synthesis of monosubstituted rhodocenium through a {"} η5 → η4 → η5{"} strategy detailing sequential nucleophilic addition and endohydride abstraction. Monosubstituted rhodocenium derivatives are then used as versatile synthons for the preparation of the first-ever vinyl monomers that allow controlled polymerizations including ROMP and RAFT, leading to rhodocenium-containing metallopolymers. Exploratory ion-exchange and self-assembly of this new class of polyelectrolytes cultivates the potential of side-chain rhodocenium-containing polymers.",

author = "Yi Yan and Deaton, \{T. Maxwell\} and Jiuyang Zhang and Hongkun He and Jeffery Hayat and Parasmani Pageni and Krzysztof Matyjaszewski and Chuanbing Tang",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = mar,

day = "24",

doi = "10.1021/acs.macromol.5b00471",

language = "English (US)",

volume = "48",

pages = "1644--1650",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Syntheses of monosubstituted rhodocenium derivatives, monomers, and polymers

AU - Yan, Yi

AU - Deaton, T. Maxwell

AU - Zhang, Jiuyang

AU - He, Hongkun

AU - Hayat, Jeffery

AU - Pageni, Parasmani

AU - Matyjaszewski, Krzysztof

AU - Tang, Chuanbing

PY - 2015/3/24

Y1 - 2015/3/24

N2 - We report the first chemoselective, high yield synthesis of monosubstituted rhodocenium through a " η5 → η4 → η5" strategy detailing sequential nucleophilic addition and endohydride abstraction. Monosubstituted rhodocenium derivatives are then used as versatile synthons for the preparation of the first-ever vinyl monomers that allow controlled polymerizations including ROMP and RAFT, leading to rhodocenium-containing metallopolymers. Exploratory ion-exchange and self-assembly of this new class of polyelectrolytes cultivates the potential of side-chain rhodocenium-containing polymers.

AB - We report the first chemoselective, high yield synthesis of monosubstituted rhodocenium through a " η5 → η4 → η5" strategy detailing sequential nucleophilic addition and endohydride abstraction. Monosubstituted rhodocenium derivatives are then used as versatile synthons for the preparation of the first-ever vinyl monomers that allow controlled polymerizations including ROMP and RAFT, leading to rhodocenium-containing metallopolymers. Exploratory ion-exchange and self-assembly of this new class of polyelectrolytes cultivates the potential of side-chain rhodocenium-containing polymers.

UR - https://www.scopus.com/pages/publications/84925430675

UR - https://www.scopus.com/pages/publications/84925430675#tab=citedBy

U2 - 10.1021/acs.macromol.5b00471

DO - 10.1021/acs.macromol.5b00471

M3 - Article

AN - SCOPUS:84925430675

SN - 0024-9297

VL - 48

SP - 1644

EP - 1650

JO - Macromolecules

JF - Macromolecules

IS - 6

ER -

Syntheses of monosubstituted rhodocenium derivatives, monomers, and polymers

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this