Syntheses and structures of quinuclidine-stabilized four- and five-coordinate mono- and di-chlorogallane

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Abstract

Hydride/chloride redistribution reactions provided high yields of GaCl2H(quin) I, GaCl2H(quin)2 II, GaClH2(quin) III and GaClH2(quin)2 IV (quin = quinuclidine) and structural characterization of compounds II and IV authenticate the unusual five-coordinate geometry for gallium hydride complexes.

Original languageEnglish (US)
Pages (from-to)123-124
Number of pages2
JournalChemical Communications
Issue number2
DOIs
StatePublished - Jan 21 1999

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