Syntheses and structural characterizations of cis-[M(NO)2(CNXyl)4]+ (M = Nb, Ta; Xyl = 2,6-Me2C6H3). The first dinitrosyls of niobium and tantalum

Mikhail V. Barybin; Victor G. Young; John E. Ellis

doi:10.1021/om990330w

Syntheses and structural characterizations of cis-[M(NO)₂(CNXyl)₄]⁺ (M = Nb, Ta; Xyl = 2,6-Me₂C₆H₃). The first dinitrosyls of niobium and tantalum

Mikhail V. Barybin, Victor G. Young, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The first dinitrosyls of niobium and tantalum, cis-[M(NO)₂(CNXyl)₄]⁺, have been prepared by direct nitrosylation of [M(CO)₆]^- (M = Nb, Ta) with 2 equiv of [NO]⁺ in the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, ¹H, and ¹³C NMR spectra as well as X-ray crystallography.

Original language	English (US)
Pages (from-to)	2744-2746
Number of pages	3
Journal	Organometallics
Volume	18
Issue number	15
DOIs	https://doi.org/10.1021/om990330w
State	Published - Jul 19 1999

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title = "Syntheses and structural characterizations of cis-[M(NO)2(CNXyl)4]+ (M = Nb, Ta; Xyl = 2,6-Me2C6H3). The first dinitrosyls of niobium and tantalum",

abstract = "The first dinitrosyls of niobium and tantalum, cis-[M(NO)2(CNXyl)4]+, have been prepared by direct nitrosylation of [M(CO)6]- (M = Nb, Ta) with 2 equiv of [NO]+ in the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, 1H, and 13C NMR spectra as well as X-ray crystallography.",

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T1 - Syntheses and structural characterizations of cis-[M(NO)2(CNXyl)4]+ (M = Nb, Ta; Xyl = 2,6-Me2C6H3). The first dinitrosyls of niobium and tantalum

AU - Barybin, Mikhail V.

AU - Young, Victor G.

AU - Ellis, John E.

PY - 1999/7/19

Y1 - 1999/7/19

N2 - The first dinitrosyls of niobium and tantalum, cis-[M(NO)2(CNXyl)4]+, have been prepared by direct nitrosylation of [M(CO)6]- (M = Nb, Ta) with 2 equiv of [NO]+ in the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, 1H, and 13C NMR spectra as well as X-ray crystallography.

AB - The first dinitrosyls of niobium and tantalum, cis-[M(NO)2(CNXyl)4]+, have been prepared by direct nitrosylation of [M(CO)6]- (M = Nb, Ta) with 2 equiv of [NO]+ in the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, 1H, and 13C NMR spectra as well as X-ray crystallography.

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Syntheses and structural characterizations of cis-[M(NO)₂(CNXyl)₄]⁺ (M = Nb, Ta; Xyl = 2,6-Me₂C₆H₃). The first dinitrosyls of niobium and tantalum

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