Syntheses and structural characterizations of cis-[M(NO)2(CNXyl)4]+ (M = Nb, Ta; Xyl = 2,6-Me2C6H3). The first dinitrosyls of niobium and tantalum

Mikhail V. Barybin, Victor G. Young, John E. Ellis

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Abstract

The first dinitrosyls of niobium and tantalum, cis-[M(NO)2(CNXyl)4]+, have been prepared by direct nitrosylation of [M(CO)6]- (M = Nb, Ta) with 2 equiv of [NO]+ in the presence of 2,6-dimethylphenyl isocyanide, CNXyl. These new complexes have been fully characterized by IR, 1H, and 13C NMR spectra as well as X-ray crystallography.

Original languageEnglish (US)
Pages (from-to)2744-2746
Number of pages3
JournalOrganometallics
Volume18
Issue number15
DOIs
StatePublished - Jul 19 1999

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