Sugar anomerism - A short and sweet digression perspective on "the application of ab initio molecular orbital theory to the anomeric effect"

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Abstract

The subject paper presented the first conformational analysis of the anomeric effect within the context of molecular orbital theory, discussed the utility of Fourier decomposition of a torsional coordinate as a method for analyzing disparate electronic influences on that coordinate, and helped settle debate on the nature of anomeric stabilization.

Original languageEnglish (US)
Pages (from-to)308-310
Number of pages3
JournalTheoretical Chemistry Accounts
Volume103
Issue number3-4
DOIs
StatePublished - Feb 2000

Keywords

  • Carbohydrate
  • Conformational analysis
  • Hyperconjugation
  • Stereoelectronic effects

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