Study on the reaction behavior of some trinuclear complexes of transition metals: [Fe2M(μ3-O)-(μ-O2CC2H 5)6 · (H2O)3] · xH2O [M=Fe(III), Mn( II ), Co( II ) and Ni( II )] by the method of probe reaction of propionic acid

Lin Na Zhang; Qing San Xie; Ling Jie He; Bo Cheng; Su Hua Cai; Yong Cui; Wen Bo Zhou

Study on the reaction behavior of some trinuclear complexes of transition metals: [Fe₂M(μ₃-O)-(μ-O₂CC₂H ₅)₆ · (H₂O)₃] · xH₂O [M=Fe(III), Mn( II ), Co( II ) and Ni( II )] by the method of probe reaction of propionic acid

Lin Na Zhang, Qing San Xie, Ling Jie He, Bo Cheng, Su Hua Cai, Yong Cui, Wen Bo Zhou

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction behaviors of the title complexes have been investigated under the dinitrogen by means of in situ IR study. It has been found that the two kinds of active species created at some stage of the thermal decomposition process of the complexes enable the propionic acid to convert to both acetaldehyde and pentanone. The universality for the ketonization reaction, the reliability of the results obtained, as well as the possible composition of the active species have been discussed to some extent in the paper. Finally, in terms of the in situ IR and GC analyses the reaction path of the formation of acetaldehyde has been tentatively elucidated too.

Original language	English (US)
Pages (from-to)	383-389
Number of pages	7
Journal	Jiegou Huaxue
Volume	17
Issue number	5
State	Published - 1998
Externally published	Yes

Keywords

In situ IR
Probe reaction
Tranuclear oxo-carboxylato complex

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Study on the reaction behavior of some trinuclear complexes of transition metals: [Fe₂M(μ₃-O)-(μ-O₂CC₂H ₅)₆ · (H₂O)₃] · xH₂O [M=Fe(III), Mn( II ), Co( II ) and Ni( II )] by the method of probe reaction of propionic acid. / Zhang, Lin Na; Xie, Qing San; He, Ling Jie et al.
In: Jiegou Huaxue, Vol. 17, No. 5, 1998, p. 383-389.

Research output: Contribution to journal › Article › peer-review

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title = "Study on the reaction behavior of some trinuclear complexes of transition metals: [Fe2M(μ3-O)-(μ-O2CC2H 5)6 · (H2O)3] · xH2O [M=Fe(III), Mn( II ), Co( II ) and Ni( II )] by the method of probe reaction of propionic acid",

abstract = "The reaction behaviors of the title complexes have been investigated under the dinitrogen by means of in situ IR study. It has been found that the two kinds of active species created at some stage of the thermal decomposition process of the complexes enable the propionic acid to convert to both acetaldehyde and pentanone. The universality for the ketonization reaction, the reliability of the results obtained, as well as the possible composition of the active species have been discussed to some extent in the paper. Finally, in terms of the in situ IR and GC analyses the reaction path of the formation of acetaldehyde has been tentatively elucidated too.",

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T2 - [Fe2M(μ3-O)-(μ-O2CC2H 5)6 · (H2O)3] · xH2O [M=Fe(III), Mn( II ), Co( II ) and Ni( II )] by the method of probe reaction of propionic acid

AU - Zhang, Lin Na

AU - Xie, Qing San

AU - He, Ling Jie

AU - Cheng, Bo

AU - Cai, Su Hua

AU - Cui, Yong

AU - Zhou, Wen Bo

PY - 1998

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AB - The reaction behaviors of the title complexes have been investigated under the dinitrogen by means of in situ IR study. It has been found that the two kinds of active species created at some stage of the thermal decomposition process of the complexes enable the propionic acid to convert to both acetaldehyde and pentanone. The universality for the ketonization reaction, the reliability of the results obtained, as well as the possible composition of the active species have been discussed to some extent in the paper. Finally, in terms of the in situ IR and GC analyses the reaction path of the formation of acetaldehyde has been tentatively elucidated too.

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KW - Probe reaction

KW - Tranuclear oxo-carboxylato complex

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