Studies toward the syntheses of functionalized, fluorinated allyl alcohols

P. V. Ramachandran; M. Venkat Ram Reddy; Michael T. Rudd

Studies toward the syntheses of functionalized, fluorinated allyl alcohols

P. V. Ramachandran
, M. Venkat Ram Reddy
, Michael T. Rudd

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.

Original language	English (US)
Pages (from-to)	117-126
Number of pages	10
Journal	ACS Symposium Series
Volume	746
State	Published - Dec 1 1999

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title = "Studies toward the syntheses of functionalized, fluorinated allyl alcohols",

abstract = "This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.",

author = "Ramachandran, \{P. V.\} and Reddy, \{M. Venkat Ram\} and Rudd, \{Michael T.\}",

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pages = "117--126",

journal = "ACS Symposium Series",

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AU - Reddy, M. Venkat Ram

AU - Rudd, Michael T.

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N2 - This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.

AB - This chapter reviews our study of Morita-Baylis-Hillman (MBH) and vinylmetalation reactions for the synthesis of achiral and chiral, functionalized, fluorinated allyl alcohols. Vinylmetalation of fluoro-carbonyls with aluminum and copper reagents for the synthesis of unsubstituted, and β-substituted fluorinated allyl alcohols is summarized. An exploratory study of terpenyl alcohols as chiral auxiliaries in these reactions is also discussed.

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UR - https://www.scopus.com/pages/publications/0042411293#tab=citedBy

M3 - Article

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SN - 0097-6156

VL - 746

SP - 117

EP - 126

JO - ACS Symposium Series

JF - ACS Symposium Series

ER -

Studies toward the syntheses of functionalized, fluorinated allyl alcohols

Abstract

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