Structures and Dynamics of Glass-Forming Colloidal Liquids under Spherical Confinement

Bo Zhang, Xiang Cheng

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of liquid relaxation. The prediction, however, has yet to be verified in 3D experiments. Here, we design a colloidal system, where particles are confined inside spherical cavities with an amorphous layer of particles pinned at the boundary. Using this novel system, we capture the amorphous-order particle clusters and demonstrate the development of a static correlation. Moreover, by investigating the dynamics of spherically confined samples, we reveal a profound influence of the static correlation on the relaxation of colloidal liquids. In analogy to glass-forming liquids with randomly pinned particles, we propose a simple relation for the change of the configurational entropy of confined colloidal liquids, which quantitatively explains our experimental findings and illustrates a divergent static length scale during the colloidal glass transition.

Original languageEnglish (US)
Article number098302
JournalPhysical review letters
Volume116
Issue number9
DOIs
StatePublished - Mar 2 2016

How much support was provided by MRSEC?

  • Partial

Reporting period for MRSEC

  • Period 3

PubMed: MeSH publication types

  • Journal Article

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