Structure and Host-Guest Interactions of Perylene-Diimide Dyes in Zeolite L Nanochannels

Lara Gigli, Rossella Arletti, Gloria Tabacchi, Marco Fabbiani, Jenny G. Vitillo, Gianmario Martra, Andre Devaux, Ivana Miletto, Simona Quartieri, Gion Calzaferri, Ettore Fois

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Confinement-driven self-assembly of dyes in nanomatrices is an effective route for the production of hybrid supramolecular structures of high technological relevance, among which the archetypal zeolite L based systems are exploited in Förster resonance energy transfer (FRET) sensitized solar cells, luminescent solar concentrators, and color-changing media but also in sensing in analytical chemistry, biology, and diagnostics. Despite this progress in applications, the organization of confined chromophores in zeolite L materials remains elusive. Herein, by integrating experiments with different time scale and radiation source (IR, XRPD, total scattering) with first-principles DFT modeling, we attained a microscopically detailed picture of a technologically important hybrid composite of zeolite L with a perylene-diimide (also known as perylene-bisimide) dye at both hydrated and anhydrous conditions. The asymmetric positioning of the dye in the zeolite channel is determined by two factors: shape-volume constraints, and relative strength of competitive interactions among confined species. Our multitechnique experimental-theoretical approach thoroughly described the supramolecular chemistry of this hybrid material, identifiying possible strategies to further enhance FRET efficiency and improve functionality. This work deepens the understanding of host-guest interactions in dye-zeolite L composites, a key requirement to master the finely tuned mechanisms governing supramolecular organization in confined nanospaces.

Original languageEnglish (US)
Pages (from-to)3401-3418
Number of pages18
JournalJournal of Physical Chemistry C
Volume122
Issue number6
DOIs
StatePublished - Feb 15 2018

Bibliographical note

Funding Information:
The BM01 beamline at the European Synchrotron Radiation Facility and Dr. Vladimir Dmitriev are acknowledged for allocation of experimental beamtime. Carlotta Giacobbe is acknowledged for the data collection at ID22 beamline. Andrea Bernasconi is acknowledged for the help in the total scattering data analysis and for constructive discussions. Dr. Simona Bigi is acknowledged for the help in TGA-MSEGA analyses. Three anonymous reviewers are acknowledged for insightful comments and suggestions. This work was supported by the Italian MIUR, (PRIN2015 “ZAPPING” High-pressure nanoconfine-ment in Zeolites: the Mineral Science know-how APPlied to engineerING of innovative materials for technological and environmental applications” 2015HK93L7), by ImPACT (FIRB RBFR12CLQD), and by Insubria University (FAR 2015-2016).

Publisher Copyright:
© 2018 American Chemical Society.

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