Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

Susana Figueroa-Gerstenmaier; Christophe Daniel; Giuseppe Milano; Gaetano Guerra; Olena Zavorotynska; Jenny G. Vitillo; Adriano Zecchina; Giuseppe Spoto

doi:10.1039/b923173k

Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

Susana Figueroa-Gerstenmaier, Christophe Daniel, Giuseppe Milano, Gaetano Guerra, Olena Zavorotynska, Jenny G. Vitillo, Adriano Zecchina, Giuseppe Spoto

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A mechanism of H₂ uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous δ phase. An ordered arrangement of the H₂ molecules is proven by FTIR spectra while the inclusion of H₂ is assessed by gravimetric measurements and molecular simulations.

Original language	English (US)
Pages (from-to)	5369-5374
Number of pages	6
Journal	Physical Chemistry Chemical Physics
Volume	12
Issue number	20
DOIs	https://doi.org/10.1039/b923173k
State	Published - 2010

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abstract = "A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous δ phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.",

author = "Susana Figueroa-Gerstenmaier and Christophe Daniel and Giuseppe Milano and Gaetano Guerra and Olena Zavorotynska and Vitillo, {Jenny G.} and Adriano Zecchina and Giuseppe Spoto",

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AU - Figueroa-Gerstenmaier, Susana

AU - Daniel, Christophe

AU - Milano, Giuseppe

AU - Guerra, Gaetano

AU - Zavorotynska, Olena

AU - Vitillo, Jenny G.

AU - Zecchina, Adriano

AU - Spoto, Giuseppe

PY - 2010

Y1 - 2010

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AB - A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous δ phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.

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JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 20

ER -

Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

Abstract

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