Abstract
The sterically crowded gallium amidinate complexes {tBuC(NR′)2}GaX2 (X = Cl, Me, Et, CH2Ph; R′ = iPr, Cy, tBu) have been synthesized in good yield. X-ray crystallographic analyses show that the steric interactions between the tBu and R′ groups influence the R′-N-Ga angle and the steric environment at gallium.
Original language | English (US) |
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Pages (from-to) | 4619-4623 |
Number of pages | 5 |
Journal | Organometallics |
Volume | 18 |
Issue number | 22 |
DOIs | |
State | Published - Oct 25 1999 |