Stereoselective and controlled polymerization of d,l-lactide using indium(iii) trichloride

Agostino Pietrangelo; Marc A. Hillmyer; William B. Tolman

doi:10.1039/b902968k

Stereoselective and controlled polymerization of d,l-lactide using indium(iii) trichloride

Agostino Pietrangelo, Marc A. Hillmyer, William B. Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of d,l-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

Original language	English (US)
Pages (from-to)	2736-2737
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/b902968k
State	Published - 2009

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title = "Stereoselective and controlled polymerization of d,l-lactide using indium(iii) trichloride",

abstract = "Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of d,l-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.",

author = "Agostino Pietrangelo and Hillmyer, {Marc A.} and Tolman, {William B.}",

year = "2009",

doi = "10.1039/b902968k",

language = "English (US)",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "19",

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T1 - Stereoselective and controlled polymerization of d,l-lactide using indium(iii) trichloride

AU - Pietrangelo, Agostino

AU - Hillmyer, Marc A.

AU - Tolman, William B.

PY - 2009

Y1 - 2009

N2 - Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of d,l-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

AB - Indium trichloride, benzyl alcohol, and triethylamine (without an added 'directing' multidentate ligand) generate a catalyst in situ for the room temperature polymerization of d,l-lactide affording highly heterotactic polylactide of controlled molecular weight and narrow molecular weight distribution.

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U2 - 10.1039/b902968k

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Stereoselective and controlled polymerization of d,l-lactide using indium(iii) trichloride

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