Stereochemistry of oxidative deiodination leading to formation of covalent perchlorates

Nikolai S. Zefirov, Viktor V. Zhdankin, Anatoly S. Koz'min

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The oxidative deiodination of several secondary iodides (1,2 and 3) in the presence of lithium perchlorate proceeds with inversion at carbon to give the corresponding perchlorates. This observation is discussed in terms of the dependence of nucleophilic reactivity of nucleofugic anions on the carbocationic character of transition state of synchronous SN processes.

Original languageEnglish (US)
Pages (from-to)1845-1846
Number of pages2
JournalTetrahedron Letters
Volume27
Issue number16
DOIs
StatePublished - 1986

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