Statistical thermodynamics of hard spheres in a narrow cylindrical pore

Qingsheng Xin, Isao Hiyane, Paul D Siders

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Statistical thermodynamics of hard spheres in a narrow right-circular cylindrical pore have been studied by the transfer-matrix method. The diameter of the pore is of the order of the particle diameter. The chemical potential and density calculated from the eigenvalues of the transfer operator show that there is no phase transition.

Original languageEnglish (US)
Pages (from-to)973-977
Number of pages5
JournalJournal of the Chemical Society, Faraday Transactions
Volume90
Issue number7
DOIs
StatePublished - Dec 1 1994

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