Stabilization of Silver and Gold Nanoparticles: Preservation and Improvement of Plasmonic Functionalities

Hyunho Kang, Joseph T. Buchman, Rebeca S. Rodriguez, Hattie L. Ring, Jiayi He, Kyle C. Bantz, Christy L. Haynes

Research output: Contribution to journalReview articlepeer-review

338 Scopus citations


Noble metal nanoparticles have been extensively studied to understand and apply their plasmonic responses, upon coupling with electromagnetic radiation, to research areas such as sensing, photocatalysis, electronics, and biomedicine. The plasmonic properties of metal nanoparticles can change significantly with changes in particle size, shape, composition, and arrangement. Thus, stabilization of the fabricated nanoparticles is crucial for preservation of the desired plasmonic behavior. Because plasmonic nanoparticles find application in diverse fields, a variety of different stabilization strategies have been developed. Often, stabilizers also function to enhance or improve the plasmonic properties of the nanoparticles. This review provides a representative overview of how gold and silver nanoparticles, the most frequently used materials in current plasmonic applications, are stabilized in different application platforms and how the stabilizing agents improve their plasmonic properties at the same time. Specifically, this review focuses on the roles and effects of stabilizing agents such as surfactants, silica, biomolecules, polymers, and metal shells in colloidal nanoparticle suspensions. Stability strategies for other types of plasmonic nanomaterials, lithographic plasmonic nanoparticle arrays, are discussed as well.

Original languageEnglish (US)
Pages (from-to)664-699
Number of pages36
JournalChemical Reviews
Issue number1
StatePublished - Jan 9 2019

Bibliographical note

Funding Information:
This work was supported by National Science Foundation under the Center for Sustainable Nanotechnology (CSN), CHE-1503408. The CSN is part of the Centers for Chemical Innovation Program. J.T.B. acknowledges support by a National Science Foundation Graduate Research Fellowship (Grant no. 00039202). Portions of this work were conducted in the Minnesota Nano Center, which is supported by the National Science Foundation through the National Nano Coordinated Infrastructure Network (NNCI) under Award Number ECCS-1542202.

Publisher Copyright:
© 2018 American Chemical Society.


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