Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

József S. Pap; Apparao Draksharapu; Michel Giorgi; Wesley R. Browne; József Kaizer; Gábor Speier

doi:10.1039/c3cc48196d

Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

József S. Pap, Apparao Draksharapu, Michel Giorgi, Wesley R. Browne, József Kaizer, Gábor Speier

Chemistry (Twin Cities)

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26 Scopus citations

Abstract

TThe spectroscopic characterisation of the (¼-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)₃]²⁺ complexes with H₂O₂ by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H₂O₂ is demonstrated.

Original language	English (US)
Pages (from-to)	1326-1329
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	11
DOIs	https://doi.org/10.1039/c3cc48196d
State	Published - Jan 9 2014

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10.1039/c3cc48196d

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title = "Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands",

abstract = "TThe spectroscopic characterisation of the (¼-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.",

author = "Pap, {J{\'o}zsef S.} and Apparao Draksharapu and Michel Giorgi and Browne, {Wesley R.} and J{\'o}zsef Kaizer and G{\'a}bor Speier",

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doi = "10.1039/c3cc48196d",

language = "English (US)",

volume = "50",

pages = "1326--1329",

journal = "Chemical Communications",

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TY - JOUR

T1 - Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

AU - Pap, József S.

AU - Draksharapu, Apparao

AU - Giorgi, Michel

AU - Browne, Wesley R.

AU - Kaizer, József

AU - Speier, Gábor

PY - 2014/1/9

Y1 - 2014/1/9

N2 - TThe spectroscopic characterisation of the (¼-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

AB - TThe spectroscopic characterisation of the (¼-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

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DO - 10.1039/c3cc48196d

M3 - Article

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EP - 1329

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

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