Stabilisation of ¼-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

József S. Pap, Apparao Draksharapu, Michel Giorgi, Wesley R. Browne, József Kaizer, Gábor Speier

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

TThe spectroscopic characterisation of the (¼-1,2-peroxido)diiron(iii) species formed transiently upon reaction of [Fe(ii)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

Original languageEnglish (US)
Pages (from-to)1326-1329
Number of pages4
JournalChemical Communications
Volume50
Issue number11
DOIs
StatePublished - Jan 9 2014

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