Splitting the coordinated nitric oxide in Co(CO)3(NO) leads to a nanocrystalline, conductive oxonitride of cobalt

Nathan R M Crawford; Jeffrey S. Knutsen; Kai Ann Yang; Greg Haugstad; Stuart McKernan; Fred B. McCormick; Wayne L. Gladfelter

Splitting the coordinated nitric oxide in Co(CO)₃(NO) leads to a nanocrystalline, conductive oxonitride of cobalt

Nathan R M Crawford, Jeffrey S. Knutsen, Kai Ann Yang, Greg Haugstad, Stuart McKernan, Fred B. McCormick, Wayne L. Gladfelter

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of tetrahedral nanocrystals of CoO from Co₂(CO)₈ was investigated. The analysis of both the amorphous and nanocrystalline components yielded compositions ranging from CoN_0.67O_1.3 to CoN_0.18O_0.72. The broad distribution in composition resulted from the variation in the processing history among the particles. The control of particle size was achieved by variation of the temperature of the precursor vessel and the partial pressure of Co(CO)₃(NO).

Original language	English (US)
Pages (from-to)	181-183
Number of pages	3
Journal	Advanced Materials
Volume	10
Issue number	14
State	Published - Oct 1 1998

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@article{d3efc05b85b4474c938b4d8bb884a30f,

title = "Splitting the coordinated nitric oxide in Co(CO)3(NO) leads to a nanocrystalline, conductive oxonitride of cobalt",

abstract = "The formation of tetrahedral nanocrystals of CoO from Co2(CO)8 was investigated. The analysis of both the amorphous and nanocrystalline components yielded compositions ranging from CoN0.67O1.3 to CoN0.18O0.72. The broad distribution in composition resulted from the variation in the processing history among the particles. The control of particle size was achieved by variation of the temperature of the precursor vessel and the partial pressure of Co(CO)3(NO).",

author = "Crawford, {Nathan R M} and Knutsen, {Jeffrey S.} and Yang, {Kai Ann} and Greg Haugstad and Stuart McKernan and McCormick, {Fred B.} and Gladfelter, {Wayne L.}",

year = "1998",

month = oct,

day = "1",

language = "English (US)",

volume = "10",

pages = "181--183",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Splitting the coordinated nitric oxide in Co(CO)3(NO) leads to a nanocrystalline, conductive oxonitride of cobalt

AU - Crawford, Nathan R M

AU - Knutsen, Jeffrey S.

AU - Yang, Kai Ann

AU - Haugstad, Greg

AU - McKernan, Stuart

AU - McCormick, Fred B.

AU - Gladfelter, Wayne L.

PY - 1998/10/1

Y1 - 1998/10/1

N2 - The formation of tetrahedral nanocrystals of CoO from Co2(CO)8 was investigated. The analysis of both the amorphous and nanocrystalline components yielded compositions ranging from CoN0.67O1.3 to CoN0.18O0.72. The broad distribution in composition resulted from the variation in the processing history among the particles. The control of particle size was achieved by variation of the temperature of the precursor vessel and the partial pressure of Co(CO)3(NO).

AB - The formation of tetrahedral nanocrystals of CoO from Co2(CO)8 was investigated. The analysis of both the amorphous and nanocrystalline components yielded compositions ranging from CoN0.67O1.3 to CoN0.18O0.72. The broad distribution in composition resulted from the variation in the processing history among the particles. The control of particle size was achieved by variation of the temperature of the precursor vessel and the partial pressure of Co(CO)3(NO).

UR - http://www.scopus.com/inward/record.url?scp=0032183285&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032183285&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0032183285

SN - 0935-9648

VL - 10

SP - 181

EP - 183

JO - Advanced Materials

JF - Advanced Materials

IS - 14

ER -

Splitting the coordinated nitric oxide in Co(CO)₃(NO) leads to a nanocrystalline, conductive oxonitride of cobalt

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