Spin state tuning of non-heme iron-catalyzed hydrocarbon oxidations: Participation of Fe^III-OOH and Fe^V=O intermediates

Keyphrases

• Hydrocarbon Oxidation 100%
• Non-heme Iron 100%
• Fe(III) 100%
• Spin State 100%
• Iron-catalyzed 100%
• Hydrogen Peroxide 66%
• Highly Stereoselective 66%
• Diols 33%
• Olefins 33%
• Oxidation Reaction 33%
• Low Spin 33%
• Higher Spin 33%
• Oxygen Atom 33%
• Acetonitrile 33%
• Olefin Epoxidation 33%
• Fe(II) 33%
• Tetradentate 33%
• Selective Hydrocarbon Oxidation 33%
• Cis-dihydroxylation 33%
• Alkane Hydroxylation 33%
• Reactivity Pattern 33%
• Pyridine Ligands 33%
• Oxidation Reactivity 33%
• Methyl Substituent 33%

Chemistry

• Spin State 100%
• Heme 100%
• Alkene 66%
• Iron Complex 66%
• Hydrogen Peroxide 66%
• Oxidation Reaction 33%
• Cis-Dihydroxylation 33%
• Hydrocarbon 33%
• Oxygen Atom 33%
• Alkane 33%
• epoxidation 33%
• hydroxylation 33%
• Diol 33%

Chemical Engineering

• Olefin 100%
• Hydrogen Peroxide 100%