Solvent-free direct cyclopalladation of sulfides on silica gel

Jonathan E. Kukowski; Jessica R. Lamb; Valeria A. Stepanova; Irina P. Smoliakova

doi:10.1016/j.inoche.2012.09.029

Solvent-free direct cyclopalladation of sulfides on silica gel

Jonathan E. Kukowski
, Jessica R. Lamb
, Valeria A. Stepanova
, Irina P. Smoliakova

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Direct cyclopalladation of benzyl methyl sulfide, benzyl phenyl sulfide and 1,3-bis(methylthiomethyl)benzene using Pd(OAc) ₂ can be accomplished using silica gel instead of a solvent. The yields of the corresponding cyclopalladated complexes in these green transformations are very similar to those obtained using conventional solvent conditions. The X-ray crystallographic data for trans-Pd(HL) ₂Cl ₂ (HL = benzyl methyl sulfide) are reported.

Original language	English (US)
Pages (from-to)	64-65
Number of pages	2
Journal	Inorganic Chemistry Communications
Volume	26
DOIs	https://doi.org/10.1016/j.inoche.2012.09.029
State	Published - Dec 2012
Externally published	Yes

Keywords

C,S-palladacycle
Cyclopalladation of sulfides
Reactions on silica gel
S,C,S-palladacycle

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10.1016/j.inoche.2012.09.029

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@article{3b8bda58f6f84aaaa248b05db54c1124,

title = "Solvent-free direct cyclopalladation of sulfides on silica gel",

abstract = "Direct cyclopalladation of benzyl methyl sulfide, benzyl phenyl sulfide and 1,3-bis(methylthiomethyl)benzene using Pd(OAc) 2 can be accomplished using silica gel instead of a solvent. The yields of the corresponding cyclopalladated complexes in these green transformations are very similar to those obtained using conventional solvent conditions. The X-ray crystallographic data for trans-Pd(HL) 2Cl 2 (HL = benzyl methyl sulfide) are reported.",

keywords = "C,S-palladacycle, Cyclopalladation of sulfides, Reactions on silica gel, S,C,S-palladacycle",

author = "Kukowski, \{Jonathan E.\} and Lamb, \{Jessica R.\} and Stepanova, \{Valeria A.\} and Smoliakova, \{Irina P.\}",

year = "2012",

month = dec,

doi = "10.1016/j.inoche.2012.09.029",

language = "English (US)",

volume = "26",

pages = "64--65",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Solvent-free direct cyclopalladation of sulfides on silica gel

AU - Kukowski, Jonathan E.

AU - Lamb, Jessica R.

AU - Stepanova, Valeria A.

AU - Smoliakova, Irina P.

PY - 2012/12

Y1 - 2012/12

N2 - Direct cyclopalladation of benzyl methyl sulfide, benzyl phenyl sulfide and 1,3-bis(methylthiomethyl)benzene using Pd(OAc) 2 can be accomplished using silica gel instead of a solvent. The yields of the corresponding cyclopalladated complexes in these green transformations are very similar to those obtained using conventional solvent conditions. The X-ray crystallographic data for trans-Pd(HL) 2Cl 2 (HL = benzyl methyl sulfide) are reported.

AB - Direct cyclopalladation of benzyl methyl sulfide, benzyl phenyl sulfide and 1,3-bis(methylthiomethyl)benzene using Pd(OAc) 2 can be accomplished using silica gel instead of a solvent. The yields of the corresponding cyclopalladated complexes in these green transformations are very similar to those obtained using conventional solvent conditions. The X-ray crystallographic data for trans-Pd(HL) 2Cl 2 (HL = benzyl methyl sulfide) are reported.

KW - C,S-palladacycle

KW - Cyclopalladation of sulfides

KW - Reactions on silica gel

KW - S,C,S-palladacycle

UR - https://www.scopus.com/pages/publications/84867747328

UR - https://www.scopus.com/pages/publications/84867747328#tab=citedBy

U2 - 10.1016/j.inoche.2012.09.029

DO - 10.1016/j.inoche.2012.09.029

M3 - Article

AN - SCOPUS:84867747328

SN - 1387-7003

VL - 26

SP - 64

EP - 65

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Solvent-free direct cyclopalladation of sulfides on silica gel

Abstract

Keywords

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