Solvent and Chloride Ion Effects on the Acid-Catalyzed Conversion of Glucose to 5-Hydroxymethylfurfural

Keyphrases

• 5-Hydroxymethylfurfural (5-HMF) 100%
• Acid-catalyzed Conversion 100%
• Chloride Effect 100%
• Chloride Ion 50%
• Acetone 30%
• Fructose Dehydration 30%
• Acetone-water 30%
• Isomerization 20%
• Dehydration 20%
• C-C Bond Formation 20%
• Fructose 20%
• Activation Free Energy 20%
• Acid-catalyzed 20%
• Glucose Isomerization 20%
• Glucose Dehydration 20%
• Humins Formation 20%
• Humin 20%
• Brønsted Acid 10%
• Group by 10%
• Catalytic System 10%
• Water System 10%
• Weak Interactions 10%
• Positively Charged 10%
• Greenway 10%
• Binding Site 10%
• Mixed Solvent 10%
• Acetone Molecules 10%
• Water Molecule 10%
• Hydroxyl Group 10%
• Transition State 10%
• Overall Yield 10%
• Water Solvent 10%
• Protonation 10%
• Catalytic Reactivity 10%
• Platform Chemicals 10%
• Low Activation 10%
• Aldol Reaction 10%
• Halide Anions 10%
• Enol Form 10%
• Acid-catalyzed Dehydration 10%
• Elementary Reaction 10%
• Formation Pathway 10%
• C Addition 10%
• Aldol Addition 10%
• Solvent Choice 10%
• Sn-based Catalysts 10%
• Transition State Structure 10%
• Ab Initio Molecular Dynamics Simulation 10%
• Carbonyl Group 10%
• Proton Ions 10%

Chemistry

• 5-Hydroxymethylfurfural 100%
• Chloride Ion 100%
• Fructose 50%
• Isomerization 40%
• Gibbs Free Energy 20%
• Aldol Addition 20%
• Binding Site 10%
• Molecular Dynamics 10%
• Transition State 10%
• Hydroxyl Group 10%
• Transition State Structure 10%
• Solvent Mixture 10%
• Halide Anion 10%
• Enol 10%
• Carbonyl Group 10%
• C-C Bond Formation 10%

Chemical Engineering

• Fructose 100%
• Gibbs Free Energy 40%