Solar Energy Storage Reactions. Thermal and Photochemical Redox Reactions of Polynuclear Rhodium Isocyanide Complexes

I. S. Sigal, Kent R. Mann, Harry B. Gray

Research output: Contribution to journalArticle

69 Scopus citations

Abstract

The binuclear Rh1 complex Rh2(bridge)42+ (or Rh22+) (bridge = 1,3-diisocyanopropane) reacts with 12 M HCl to form H2 and (Rh2(bridge)4)2Cl24+ (or Rh4Cl24+). Air oxidation of 1 N H2SO4 solutions of Rh22+ produces (Rh2(bridge)4)26+ (or Rh46+).

Original languageEnglish (US)
Pages (from-to)7252-7256
Number of pages5
JournalJournal of the American Chemical Society
Volume102
Issue number24
DOIs
StatePublished - Sep 1980

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