Abstract
A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 15680-15683 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 137 |
| Issue number | 50 |
| DOIs | |
| State | Published - Dec 23 2015 |
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Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. / Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua; Gallagher, James R.; Stalzer, Madelyn M.; Miller, Jeffrey T.; Gagliardi, Laura; Hupp, Joseph T.; Marks, Tobin J.; Cramer, Christopher J.; Delferro, Massimiliano; Farha, Omar K.
In: Journal of the American Chemical Society, Vol. 137, No. 50, 23.12.2015, p. 15680-15683.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework
AU - Klet, Rachel C.
AU - Tussupbayev, Samat
AU - Borycz, Joshua
AU - Gallagher, James R.
AU - Stalzer, Madelyn M.
AU - Miller, Jeffrey T.
AU - Gagliardi, Laura
AU - Hupp, Joseph T.
AU - Marks, Tobin J.
AU - Cramer, Christopher J.
AU - Delferro, Massimiliano
AU - Farha, Omar K.
PY - 2015/12/23
Y1 - 2015/12/23
N2 - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.
AB - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.
UR - http://www.scopus.com/inward/record.url?scp=84952778416&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84952778416&partnerID=8YFLogxK
U2 - 10.1021/jacs.5b11350
DO - 10.1021/jacs.5b11350
M3 - Article
C2 - 26652625
AN - SCOPUS:84952778416
VL - 137
SP - 15680
EP - 15683
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 50
ER -