Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet; Samat Tussupbayev; Joshua Borycz; James R. Gallagher; Madelyn M. Stalzer; Jeffrey T. Miller; Laura Gagliardi; Joseph T. Hupp; Tobin J. Marks; Christopher J. Cramer; Massimiliano Delferro; Omar K. Farha

doi:10.1021/jacs.5b11350

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet, Samat Tussupbayev, Joshua Borycz, James R. Gallagher, Madelyn M. Stalzer, Jeffrey T. Miller, Laura Gagliardi, Joseph T. Hupp, Tobin J. Marks, Christopher J. Cramer, Massimiliano Delferro, Omar K. Farha

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d⁰ Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

Original language	English (US)
Pages (from-to)	15680-15683
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	50
DOIs	https://doi.org/10.1021/jacs.5b11350
State	Published - Dec 23 2015

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

Publisher link

10.1021/jacs.5b11350

Find It

Find It at U of M Libraries

Cite this

@article{5b29b790a7434fa2b8a8750f7c019c4b,

title = "Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework",

abstract = "A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.",

author = "Klet, {Rachel C.} and Samat Tussupbayev and Joshua Borycz and Gallagher, {James R.} and Stalzer, {Madelyn M.} and Miller, {Jeffrey T.} and Laura Gagliardi and Hupp, {Joseph T.} and Marks, {Tobin J.} and Cramer, {Christopher J.} and Massimiliano Delferro and Farha, {Omar K.}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = dec,

day = "23",

doi = "10.1021/jacs.5b11350",

language = "English (US)",

volume = "137",

pages = "15680--15683",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "50",

}

TY - JOUR

T1 - Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

AU - Klet, Rachel C.

AU - Tussupbayev, Samat

AU - Borycz, Joshua

AU - Gallagher, James R.

AU - Stalzer, Madelyn M.

AU - Miller, Jeffrey T.

AU - Gagliardi, Laura

AU - Hupp, Joseph T.

AU - Marks, Tobin J.

AU - Cramer, Christopher J.

AU - Delferro, Massimiliano

AU - Farha, Omar K.

PY - 2015/12/23

Y1 - 2015/12/23

N2 - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

AB - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

UR - http://www.scopus.com/inward/record.url?scp=84952778416&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84952778416&partnerID=8YFLogxK

U2 - 10.1021/jacs.5b11350

DO - 10.1021/jacs.5b11350

M3 - Article

C2 - 26652625

AN - SCOPUS:84952778416

SN - 0002-7863

VL - 137

SP - 15680

EP - 15683

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 50

ER -

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Energy Frontier Research Center For Inorganometallic Catalyst Design (DE-SC0012702)

Cite this

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Projects

Energy Frontier Research Center For Inorganometallic Catalyst Design (DE-SC0012702)

Cite this