Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet, Samat Tussupbayev, Joshua Borycz, James R. Gallagher, Madelyn M. Stalzer, Jeffrey T. Miller, Laura Gagliardi, Joseph T. Hupp, Tobin J. Marks, Christopher J. Cramer, Massimiliano Delferro, Omar K. Farha

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

Original languageEnglish (US)
Pages (from-to)15680-15683
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number50
DOIs
StatePublished - Dec 23 2015

Fingerprint

Polymerization
Metals
Catalysts
Discrete Fourier transforms
Scaffolds
Ethylene
1-hexene
ethylene

Cite this

Klet, R. C., Tussupbayev, S., Borycz, J., Gallagher, J. R., Stalzer, M. M., Miller, J. T., ... Farha, O. K. (2015). Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. Journal of the American Chemical Society, 137(50), 15680-15683. https://doi.org/10.1021/jacs.5b11350

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. / Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua; Gallagher, James R.; Stalzer, Madelyn M.; Miller, Jeffrey T.; Gagliardi, Laura; Hupp, Joseph T.; Marks, Tobin J.; Cramer, Christopher J.; Delferro, Massimiliano; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 137, No. 50, 23.12.2015, p. 15680-15683.

Research output: Contribution to journalArticle

Klet, RC, Tussupbayev, S, Borycz, J, Gallagher, JR, Stalzer, MM, Miller, JT, Gagliardi, L, Hupp, JT, Marks, TJ, Cramer, CJ, Delferro, M & Farha, OK 2015, 'Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework', Journal of the American Chemical Society, vol. 137, no. 50, pp. 15680-15683. https://doi.org/10.1021/jacs.5b11350
Klet RC, Tussupbayev S, Borycz J, Gallagher JR, Stalzer MM, Miller JT et al. Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. Journal of the American Chemical Society. 2015 Dec 23;137(50):15680-15683. https://doi.org/10.1021/jacs.5b11350
Klet, Rachel C. ; Tussupbayev, Samat ; Borycz, Joshua ; Gallagher, James R. ; Stalzer, Madelyn M. ; Miller, Jeffrey T. ; Gagliardi, Laura ; Hupp, Joseph T. ; Marks, Tobin J. ; Cramer, Christopher J. ; Delferro, Massimiliano ; Farha, Omar K. / Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. In: Journal of the American Chemical Society. 2015 ; Vol. 137, No. 50. pp. 15680-15683.
@article{5b29b790a7434fa2b8a8750f7c019c4b,
title = "Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework",
abstract = "A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.",
author = "Klet, {Rachel C.} and Samat Tussupbayev and Joshua Borycz and Gallagher, {James R.} and Stalzer, {Madelyn M.} and Miller, {Jeffrey T.} and Laura Gagliardi and Hupp, {Joseph T.} and Marks, {Tobin J.} and Cramer, {Christopher J.} and Massimiliano Delferro and Farha, {Omar K.}",
year = "2015",
month = "12",
day = "23",
doi = "10.1021/jacs.5b11350",
language = "English (US)",
volume = "137",
pages = "15680--15683",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "50",

}

TY - JOUR

T1 - Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

AU - Klet, Rachel C.

AU - Tussupbayev, Samat

AU - Borycz, Joshua

AU - Gallagher, James R.

AU - Stalzer, Madelyn M.

AU - Miller, Jeffrey T.

AU - Gagliardi, Laura

AU - Hupp, Joseph T.

AU - Marks, Tobin J.

AU - Cramer, Christopher J.

AU - Delferro, Massimiliano

AU - Farha, Omar K.

PY - 2015/12/23

Y1 - 2015/12/23

N2 - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

AB - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

UR - http://www.scopus.com/inward/record.url?scp=84952778416&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84952778416&partnerID=8YFLogxK

U2 - 10.1021/jacs.5b11350

DO - 10.1021/jacs.5b11350

M3 - Article

C2 - 26652625

AN - SCOPUS:84952778416

VL - 137

SP - 15680

EP - 15683

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 50

ER -