Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation

Saravanakumar T. Pillai; Tom Fischer; Tyler T. Clikeman; Jennifer Esbenshade; Catherine Berdanier; Heather Rohwer; Mark Jastram; Wonjun Kang; Choumini Balasanthiran; Charles S. Spanjers; Talgat Inerbaev; Dmitri S. Kilin; Robert M. Rioux; James D. Hoefelmeyer

doi:10.1021/bk-2015-1196.ch004

Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation

Saravanakumar T. Pillai
, Tom Fischer
, Tyler T. Clikeman
, Jennifer Esbenshade
, Catherine Berdanier
, Heather Rohwer
, Mark Jastram
, Wonjun Kang
, Choumini Balasanthiran
, Charles S. Spanjers
, Talgat Inerbaev
, Dmitri S. Kilin
, Robert M. Rioux
, James D. Hoefelmeyer

Chemical Engineering and Materials Science

Research output: Chapter in Book/Report/Conference proceeding › Chapter

3 Scopus citations

Abstract

We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

Original language	English (US)
Title of host publication	Photoinduced Processes at Surfaces and in Nanomaterials
Editors	Dmitri Kilin
Publisher	American Chemical Society
Pages	103-116
Number of pages	14
ISBN (Electronic)	9780841230941
DOIs	https://doi.org/10.1021/bk-2015-1196.ch004
State	Published - 2015

Publication series

Name	ACS Symposium Series
Volume	1196
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

Publisher link

10.1021/bk-2015-1196.ch004

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Cite this

Pillai, S. T., Fischer, T., Clikeman, T. T., Esbenshade, J., Berdanier, C., Rohwer, H., Jastram, M., Kang, W., Balasanthiran, C., Spanjers, C. S., Inerbaev, T., Kilin, D. S., Rioux, R. M., & Hoefelmeyer, J. D. (2015). Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. In D. Kilin (Ed.), Photoinduced Processes at Surfaces and in Nanomaterials (pp. 103-116). (ACS Symposium Series; Vol. 1196). American Chemical Society. https://doi.org/10.1021/bk-2015-1196.ch004

Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. / Pillai, Saravanakumar T.; Fischer, Tom; Clikeman, Tyler T. et al.
Photoinduced Processes at Surfaces and in Nanomaterials. ed. / Dmitri Kilin. American Chemical Society, 2015. p. 103-116 (ACS Symposium Series; Vol. 1196).

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Pillai, ST, Fischer, T, Clikeman, TT, Esbenshade, J, Berdanier, C, Rohwer, H, Jastram, M, Kang, W, Balasanthiran, C, Spanjers, CS, Inerbaev, T, Kilin, DS, Rioux, RM & Hoefelmeyer, JD 2015, Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. in D Kilin (ed.), Photoinduced Processes at Surfaces and in Nanomaterials. ACS Symposium Series, vol. 1196, American Chemical Society, pp. 103-116. https://doi.org/10.1021/bk-2015-1196.ch004

Pillai ST, Fischer T, Clikeman TT, Esbenshade J, Berdanier C, Rohwer H et al. Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. In Kilin D, editor, Photoinduced Processes at Surfaces and in Nanomaterials. American Chemical Society. 2015. p. 103-116. (ACS Symposium Series). doi: 10.1021/bk-2015-1196.ch004

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abstract = "We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.",

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doi = "10.1021/bk-2015-1196.ch004",

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AB - We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

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