Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

Gereon M. Yee, Kristin Kowolik, Shuhei Manabe, James C. Fettinger, Louise A. Berben

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.

Original languageEnglish (US)
Pages (from-to)11680-11682
Number of pages3
JournalChemical Communications
Volume47
Issue number42
DOIs
StatePublished - Nov 14 2011

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