Abstract
Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.
Original language | English (US) |
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Pages (from-to) | 11680-11682 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 47 |
Issue number | 42 |
DOIs | |
State | Published - Nov 14 2011 |