Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

Gereon M. Yee; Kristin Kowolik; Shuhei Manabe; James C. Fettinger; Louise A. Berben

doi:10.1039/c1cc14758g

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

Gereon M. Yee, Kristin Kowolik, Shuhei Manabe, James C. Fettinger, Louise A. Berben

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

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Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.

Original language	English (US)
Pages (from-to)	11680-11682
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	42
DOIs	https://doi.org/10.1039/c1cc14758g
State	Published - Nov 14 2011

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abstract = "Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.",

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T1 - Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

AU - Yee, Gereon M.

AU - Kowolik, Kristin

AU - Manabe, Shuhei

AU - Fettinger, James C.

AU - Berben, Louise A.

PY - 2011/11/14

Y1 - 2011/11/14

N2 - Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.

AB - Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl) phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(iii), Fe(ii), and Mn(ii) (3-5). Complexes 3-5 are high-spin and redox active.

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IS - 42

ER -

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

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