Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Rohit Singh; Mihai S. Viciu; Natalia Kramareva; Oscar Navarro; Steven P. Nolan

doi:10.1021/ol050472o

Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Rohit Singh
, Mihai S. Viciu
, Natalia Kramareva
, Oscar Navarro
, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

212 Scopus citations

Abstract

(Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

Original language	English (US)
Pages (from-to)	1829-1832
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	9
DOIs	https://doi.org/10.1021/ol050472o
State	Published - Apr 28 2005
Externally published	Yes

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10.1021/ol050472o

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title = "Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings",

abstract = "(Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.",

author = "Rohit Singh and Viciu, \{Mihai S.\} and Natalia Kramareva and Oscar Navarro and Nolan, \{Steven P.\}",

year = "2005",

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doi = "10.1021/ol050472o",

language = "English (US)",

volume = "7",

pages = "1829--1832",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

AU - Singh, Rohit

AU - Viciu, Mihai S.

AU - Kramareva, Natalia

AU - Navarro, Oscar

AU - Nolan, Steven P.

PY - 2005/4/28

Y1 - 2005/4/28

N2 - (Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

AB - (Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

UR - https://www.scopus.com/pages/publications/18844421600

UR - https://www.scopus.com/pages/publications/18844421600#tab=citedBy

U2 - 10.1021/ol050472o

DO - 10.1021/ol050472o

M3 - Article

C2 - 15844917

AN - SCOPUS:18844421600

SN - 1523-7060

VL - 7

SP - 1829

EP - 1832

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Abstract

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