Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Rohit Singh; Mihai S. Viciu; Natalia Kramareva; Oscar Navarro; Steven P. Nolan

doi:10.1021/ol050472o

Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Rohit Singh, Mihai S. Viciu, Natalia Kramareva, Oscar Navarro, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

209 Scopus citations

Abstract

(Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

Original language	English (US)
Pages (from-to)	1829-1832
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	9
DOIs	https://doi.org/10.1021/ol050472o
State	Published - Apr 28 2005
Externally published	Yes

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title = "Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings",

abstract = "(Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.",

author = "Rohit Singh and Viciu, {Mihai S.} and Natalia Kramareva and Oscar Navarro and Nolan, {Steven P.}",

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T1 - Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

AU - Singh, Rohit

AU - Viciu, Mihai S.

AU - Kramareva, Natalia

AU - Navarro, Oscar

AU - Nolan, Steven P.

PY - 2005/4/28

Y1 - 2005/4/28

N2 - (Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

AB - (Chemical Equation Presented) A simplified synthesis of N-heterocyclic carbene (NHC)Pd-carboxylate complexes and their activity in Suzuki-Miyaura cross-coupling reactions are described. Coupling of sterically hindered aryl and activated alkyl chlorides bearing β-hydrogens has been successfully achieved.

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Simple (imidazol-2-ylidene)-Pd-acetate complexes as effective precatalysts for sterically hindered suzuki-miyaura couplings

Abstract

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