Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen; Teng Wang; Chong Qin; Ning Jiao

doi:10.1002/anie.201300193

Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Tao Shen, Teng Wang, Chong Qin, Ning Jiao

Research output: Contribution to journal › Article › peer-review

159 Scopus citations

Abstract

Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.

Original language	English (US)
Pages (from-to)	6677-6680
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	26
DOIs	https://doi.org/10.1002/anie.201300193
State	Published - Jun 24 2013
Externally published	Yes

Keywords

alkynes
azides
nitriles
rearrangement
silver

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10.1002/anie.201300193

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abstract = "Three in one blow! A novel direct transformation of alkynes into nitriles by a silver-catalyzed nitrogenation reaction through C≡C bond cleavage has been developed. This research provides both a new application for alkynes in organic synthesis, and valuable mechanistic insights into nitrogenation chemistry.",

keywords = "alkynes, azides, nitriles, rearrangement, silver",

author = "Tao Shen and Teng Wang and Chong Qin and Ning Jiao",

year = "2013",

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T2 - A direct approach to nitriles through C≡C bond cleavage

AU - Shen, Tao

AU - Wang, Teng

AU - Qin, Chong

AU - Jiao, Ning

PY - 2013/6/24

Y1 - 2013/6/24

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KW - alkynes

KW - azides

KW - nitriles

KW - rearrangement

KW - silver

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Silver-catalyzed nitrogenation of alkynes: A direct approach to nitriles through C≡C bond cleavage

Abstract

Keywords

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