Silicon tethered ring-closing metathesis reactions for self- and cross- coupling of alkenols

Thomas R. Hoye; Michele A. Promo

doi:10.1016/S0040-4039(98)02697-5

Silicon tethered ring-closing metathesis reactions for self- and cross- coupling of alkenols

Thomas R. Hoye, Michele A. Promo

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors.

Original language	English (US)
Pages (from-to)	1429-1432
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	8
DOIs	https://doi.org/10.1016/S0040-4039(98)02697-5
State	Published - Feb 19 1999

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title = "Silicon tethered ring-closing metathesis reactions for self- and cross- coupling of alkenols",

abstract = "The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors.",

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AU - Hoye, Thomas R.

AU - Promo, Michele A.

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N2 - The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors.

AB - The title process can be used to couple allylic, homoallylic, and bishomoallylic alkenols. Cyclic silaketals with ring sizes from 7-11 members can all be formed. This constitutes a general and versatile strategy for approximately doubling the molecular complexity of readily available alkenol precursors.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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