Abstract
The oxorhenium(V) complexes with ligands containing N4 (H2pmen) N4O2 (H2bbpen, H2Clbbpen, and H2-bped) donor atom sets have been synthesized. X-ray crystallographic analyses of the [ReO(H2pmen)Cl2]+, [ReO-;(bbpen)]+, and [ReO(bped)] complexes showed that all three cations share a rare seven-coordinate structure with a distorted pentagonal bipyramidal geometry, which represents a novel and potentially general structural motif in ReV=O complexes. 1H NMR spectroscopy shows that the structures of the complexes are retained in the solution.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5958-5963 |
| Number of pages | 6 |
| Journal | Inorganic Chemistry |
| Volume | 39 |
| Issue number | 26 |
| DOIs | |
| State | Published - Dec 25 2000 |
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Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl). / Xu, L.; Setyawati, I. A.; Pierreroy, J.; Pink, M.; Young, V. G.; Patrick, B. O.; Rettig, S. J.; Orvig, C.
In: Inorganic Chemistry, Vol. 39, No. 26, 25.12.2000, p. 5958-5963.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl)
AU - Xu, L.
AU - Setyawati, I. A.
AU - Pierreroy, J.
AU - Pink, M.
AU - Young, V. G.
AU - Patrick, B. O.
AU - Rettig, S. J.
AU - Orvig, C.
PY - 2000/12/25
Y1 - 2000/12/25
N2 - The oxorhenium(V) complexes with ligands containing N4 (H2pmen) N4O2 (H2bbpen, H2Clbbpen, and H2-bped) donor atom sets have been synthesized. X-ray crystallographic analyses of the [ReO(H2pmen)Cl2]+, [ReO-;(bbpen)]+, and [ReO(bped)] complexes showed that all three cations share a rare seven-coordinate structure with a distorted pentagonal bipyramidal geometry, which represents a novel and potentially general structural motif in ReV=O complexes. 1H NMR spectroscopy shows that the structures of the complexes are retained in the solution.
AB - The oxorhenium(V) complexes with ligands containing N4 (H2pmen) N4O2 (H2bbpen, H2Clbbpen, and H2-bped) donor atom sets have been synthesized. X-ray crystallographic analyses of the [ReO(H2pmen)Cl2]+, [ReO-;(bbpen)]+, and [ReO(bped)] complexes showed that all three cations share a rare seven-coordinate structure with a distorted pentagonal bipyramidal geometry, which represents a novel and potentially general structural motif in ReV=O complexes. 1H NMR spectroscopy shows that the structures of the complexes are retained in the solution.
UR - http://www.scopus.com/inward/record.url?scp=0034716052&partnerID=8YFLogxK
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U2 - 10.1021/ic001273y
DO - 10.1021/ic001273y
M3 - Article
C2 - 11188520
AN - SCOPUS:0034716052
VL - 39
SP - 5958
EP - 5963
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 26
ER -