Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl)

L. Xu, I. A. Setyawati, J. Pierreroy, M. Pink, V. G. Young, B. O. Patrick, S. J. Rettig, C. Orvig

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Abstract

The oxorhenium(V) complexes with ligands containing N4 (H2pmen) N4O2 (H2bbpen, H2Clbbpen, and H2-bped) donor atom sets have been synthesized. X-ray crystallographic analyses of the [ReO(H2pmen)Cl2]+, [ReO-;(bbpen)]+, and [ReO(bped)] complexes showed that all three cations share a rare seven-coordinate structure with a distorted pentagonal bipyramidal geometry, which represents a novel and potentially general structural motif in ReV=O complexes. 1H NMR spectroscopy shows that the structures of the complexes are retained in the solution.

Original languageEnglish (US)
Pages (from-to)5958-5963
Number of pages6
JournalInorganic Chemistry
Volume39
Issue number26
DOIs
StatePublished - Dec 25 2000

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Nuclear magnetic resonance spectroscopy
Cations
Ligands
cations
X rays
Atoms
nuclear magnetic resonance
ligands
Geometry
geometry
spectroscopy
atoms
x rays
oligomycin sensitivity-conferring protein
perrhenate

Cite this

Xu, L., Setyawati, I. A., Pierreroy, J., Pink, M., Young, V. G., Patrick, B. O., ... Orvig, C. (2000). Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl). Inorganic Chemistry, 39(26), 5958-5963. https://doi.org/10.1021/ic001273y

Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl). / Xu, L.; Setyawati, I. A.; Pierreroy, J.; Pink, M.; Young, V. G.; Patrick, B. O.; Rettig, S. J.; Orvig, C.

In: Inorganic Chemistry, Vol. 39, No. 26, 25.12.2000, p. 5958-5963.

Research output: Contribution to journalArticle

Xu, L, Setyawati, IA, Pierreroy, J, Pink, M, Young, VG, Patrick, BO, Rettig, SJ & Orvig, C 2000, 'Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl)', Inorganic Chemistry, vol. 39, no. 26, pp. 5958-5963. https://doi.org/10.1021/ic001273y
Xu L, Setyawati IA, Pierreroy J, Pink M, Young VG, Patrick BO et al. Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl). Inorganic Chemistry. 2000 Dec 25;39(26):5958-5963. https://doi.org/10.1021/ic001273y
Xu, L. ; Setyawati, I. A. ; Pierreroy, J. ; Pink, M. ; Young, V. G. ; Patrick, B. O. ; Rettig, S. J. ; Orvig, C. / Seven-coordinate [ReVON4X2]+ complexes (X = O and Cl). In: Inorganic Chemistry. 2000 ; Vol. 39, No. 26. pp. 5958-5963.
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