Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Limin Ren; Qiang Guo; Prashant Kumar; Marat Orazov; Dandan Xu; Saeed M. Alhassan; K. Andre Mkhoyan; Mark E. Davis; Michael Tsapatsis

doi:10.1002/anie.201505334

Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Limin Ren
, Qiang Guo
, Prashant Kumar
, Marat Orazov
, Dandan Xu
, Saeed M. Alhassan
, K. Andre Mkhoyan
, Mark E. Davis
, Michael Tsapatsis

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

166 Scopus citations

Abstract

Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yields for the conversion of glucose into fructose and lactose to lactulose are demonstrated.

Original language	English (US)
Pages (from-to)	10848-10851
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	37
DOIs	https://doi.org/10.1002/anie.201505334
State	Published - Sep 1 2015

Bibliographical note

Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

heterogeneous catalysis
layered materials
nanosheets
self-pillared structures
zeolite

Publisher link

10.1002/anie.201505334

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abstract = "Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yields for the conversion of glucose into fructose and lactose to lactulose are demonstrated.",

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doi = "10.1002/anie.201505334",

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T1 - Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

AU - Ren, Limin

AU - Guo, Qiang

AU - Kumar, Prashant

AU - Orazov, Marat

AU - Xu, Dandan

AU - Alhassan, Saeed M.

AU - Mkhoyan, K. Andre

AU - Davis, Mark E.

AU - Tsapatsis, Michael

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yields for the conversion of glucose into fructose and lactose to lactulose are demonstrated.

AB - Single-unit-cell Sn-MFI, with the detectable Sn uniformly distributed and exclusively located at framework sites, is reported for the first time. The direct, single-step, synthesis is based on repetitive branching caused by rotational intergrowths of single-unit-cell lamellae. The self-pillared, meso- and microporous zeolite is an active and selective catalyst for sugar isomerization. High yields for the conversion of glucose into fructose and lactose to lactulose are demonstrated.

KW - heterogeneous catalysis

KW - layered materials

KW - nanosheets

KW - self-pillared structures

KW - zeolite

UR - https://www.scopus.com/pages/publications/84940722113

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M3 - Article

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AN - SCOPUS:84940722113

SN - 1433-7851

VL - 54

SP - 10848

EP - 10851

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 37

ER -

Self-Pillared, Single-Unit-Cell Sn-MFI Zeolite Nanosheets and Their Use for Glucose and Lactose Isomerization

Abstract

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Keywords

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