Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

Mandapati V. Ramakrishnam Raju; Hong Cheu Lin

doi:10.1021/ol5025629

Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

Mandapati V. Ramakrishnam Raju, Hong Cheu Lin

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.

Original language	English (US)
Pages (from-to)	5564-5567
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	21
DOIs	https://doi.org/10.1021/ol5025629
State	Published - Nov 7 2014

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title = "Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission",

abstract = "A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.",

author = "{Ramakrishnam Raju}, {Mandapati V.} and Lin, {Hong Cheu}",

year = "2014",

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PY - 2014/11/7

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AB - A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.

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