Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

Mandapati V. Ramakrishnam Raju; Hong Cheu Lin

doi:10.1021/ol5025629

Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

Mandapati V. Ramakrishnam Raju, Hong Cheu Lin

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.

Original language	English (US)
Pages (from-to)	5564-5567
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	21
DOIs	https://doi.org/10.1021/ol5025629
State	Published - Nov 7 2014

Bibliographical note

Publisher Copyright:
© 2014 American Chemical Society.

Publisher link

10.1021/ol5025629

Find It

Find It at U of M Libraries

Cite this

@article{1c530fa9c6444429818a89d998e3b823,

title = "Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission",

abstract = "A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.",

author = "{Ramakrishnam Raju}, {Mandapati V.} and Lin, {Hong Cheu}",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

month = nov,

day = "7",

doi = "10.1021/ol5025629",

language = "English (US)",

volume = "16",

pages = "5564--5567",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

AU - Ramakrishnam Raju, Mandapati V.

AU - Lin, Hong Cheu

PY - 2014/11/7

Y1 - 2014/11/7

N2 - A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.

AB - A novel [2]catenane 2-C based on the tetraphenylethene (TPE) and orthogonal H-bonded cleft was successfully constructed. VT-NMR and TEM measurements demonstrate that 2-C could be self-assembled to induce an enabled aggregation-induced emission (AIE) in aqueous solution and solid state owing to its TPE unit as well as present unique acid-base controllable and reversible supramolecular self-assembled nanosuperstructures by interplay of a wide range of noncovalent interactions.

UR - http://www.scopus.com/inward/record.url?scp=84910020613&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84910020613&partnerID=8YFLogxK

U2 - 10.1021/ol5025629

DO - 10.1021/ol5025629

M3 - Article

C2 - 25341492

AN - SCOPUS:84910020613

SN - 1523-7060

VL - 16

SP - 5564

EP - 5567

JO - Organic Letters

JF - Organic Letters

IS - 21

ER -

Self-assembly of tetraphenylethene-based [2]catenane driven by acid-base-controllable molecular switching and its enabled aggregation-induced emission

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this