Selective, Tunable O₂ Binding in Cobalt(II)-Triazolate/Pyrazolate Metal-Organic Frameworks

Keyphrases

• Metal-organic Frameworks (MOFs) 100%
• Cobalt(II) 100%
• Pyrazolate 100%
• O2 Binding 100%
• Triazolate 100%
• Low Spin 66%
• Methanol 33%
• Dioxygen 33%
• Benzene 33%
• Superoxo 33%
• Computational Study 33%
• Cobalt 33%
• Electron Transfer 33%
• Linker 33%
• Binding Site 33%
• Metal Center 33%
• Desolvation 33%
• Electron-donating 33%
• Electronic Structure Calculations 33%
• Isostructural 33%
• Bond Distance 33%
• Electronic Configuration 33%
• Low Pt Loading 33%
• Magnetic Susceptibility 33%
• N,N-dimethylformamide 33%
• Adsorption Capacity 33%
• Cobalt Complex 33%
• Phosgene 33%
• Phenylene 33%
• Sodalite 33%
• Single Crystal X-ray Structure 33%
• Coordinatively Unsaturated 33%
• Pyrazol 33%
• O2 Affinity 33%
• New Adsorbent 33%
• X-ray Structure Determination 33%
• 1,2,3-Triazol 33%
• Isosteric Heat of Adsorption 33%
• O2 Adsorption 33%
• Air Separation 33%
• 1H-1,2,3-triazole 33%
• 1H-1 33%
• Stronger Binding 33%

Chemistry

• Metal Organic Framework 100%
• Cobalt 100%
• Binding Site 20%
• Dioxygen 20%
• Adsorbent 20%
• Electronic State 20%
• Methanol 20%
• Single Crystalline Solid 20%
• X-Ray Diffraction 20%
• N,N-Dimethylformamide 20%
• Desolvation 20%
• Heat of Adsorption 20%
• Type Metal 20%
• Air Separation 20%
• 1H-1,2,3-triazole 20%
• electronics 20%
• Electron Transport 20%
• Magnetic Permeability 20%
• stability 20%
• formation 20%
• Benzene 20%

Material Science

• Metal-Organic Framework 100%
• Cobalt 100%
• Electron Transfer 20%
• X-Ray Diffraction 20%
• Electronic Structure Calculation 20%
• Magnetic Susceptibility 20%
• Heat of Adsorption 20%
• Type Metal 20%
• Single Crystal 20%
• Adsorbent 20%